Positronium is an electron bound to a positron

PHYSICS · Multi-part · Fermi University Physics · Quantum Mechanics · Atomic, Molecular & Optical Physics · One-electron atoms and the origins of atomic structure

Quantum Mechanics: From the Photon to the Hydrogen Atom, Ch The hydrogen atom

Problem

Positronium is an electron bound to a positron, a particle of the same mass and of charge +e+e. The Coulomb potential energy is the same −e2/4πϵ0r-e^2/4\pi\epsilon_0r as in hydrogen, but because the two masses are equal, the mass entering the radial equation is the reduced mass, whose value is quoted as mr=me/2m_r = m_e/2. In this chapter's scaling, replacing mem_e by a mass mm multiplies the energy scale by m/mem/m_e. Take 13.613.6 eV as the hydrogen energy scale and hc=1240hc = 1240 eV nm. Estimate, to two significant figures and ignoring annihilation and every splitting beyond this treatment: ((a)) the ground-state energy of positronium, in eV; ((b)) the wavelength of its n=2→n=1n = 2 \to n = 1 line, in nm.

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