PHYSICS · Multi-part · Fermi University Physics · Atomic, Molecular & Optical Physics · Many-electron atoms and the periodic table · Radiative transitions, external fields and collisions
Reading the Spectrum, Ch Atoms in a magnetic field: moments, the Zeeman effect and the Paschen-Back limit
Problem
Potassium's D1 line (λ=769.90nm) is the transition 4p2P1/2→4s2S1/2. A field B=0.80T is applied along z^.
((a)) Calculate gJ for the upper level from the Lande formula (the lower level's gJ=2, as for any 2S1/2 level).
((b)) List the mJ sublevel shifts of both levels in units of μBB, and use ΔmJ=0,±1 to find the allowed line shifts, also in units of μBB.
((c)) Convert the shifts into wavelength separations from λ0=769.90nm, in nm.