The calcium resonance line at is emitted in the transition : in both levels the spins…
PHYSICS · Multi-part · Fermi University Physics · Atomic, Molecular & Optical Physics · Radiative transitions, external fields and collisions · Radiative transitions, external fields and collisions
Reading the Spectrum, Ch Atoms in a magnetic field: moments, the Zeeman effect and the Paschen-Back limit
Problem
The calcium resonance line at 422.7nm is emitted in the transition 4p1P1→4s1S0: in both levels the spins of calcium's two outer electrons cancel, so the levels carry no net spin moment, J=L for each, and the normal Zeeman pattern applies exactly. A field B=1.5T is applied.
((a)) Predict the number of distinct line positions seen (i) viewing across the field and (ii) viewing along the field.
((b)) Calculate the wavelength separation Δλ between each outer component and the unshifted line, using Δλ=λ2Δν~.