A quenched blend has free-energy curvature per site

PHYSICS · Multi-part · Fermi University Physics · Thermal, Statistical & Complex Systems · Condensed Matter, Materials & Soft Matter · Non-equilibrium statistical mechanics and stochastic thermodynamics

Soft Matter at the Thermal Scale, Ch Spinodal decomposition and coarsening

Problem

A quenched blend has free-energy curvature f′′(12)=−0.006 kBTf''(\tfrac12) = -0.006\,k_BT per site, gradient coefficient κg=0.12 kBT nm2\kappa_g = 0.12\,k_BT\,\mathrm{nm^2} per site, and mobility M=0.02 nm2 (kBT s)−1M = 0.02\,\mathrm{nm^2}\,(k_BT\,\mathrm{s})^{-1}. ((a)) Find the fastest-growing wavevector qmq_m and wavelength λm\lambda_m. ((b)) Find the maximum growth rate Rmax⁡=Mf′′2/(4κg)R_{\max} = Mf''^2/(4\kappa_g) and the characteristic time 1/Rmax⁡1/R_{\max} for the amplitude of that mode to grow by a factor ee.

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