Solid State Physics, Ch Seeing atoms: electron and scanning-probe microscopy
Problem
Model the vacuum gap between a scanning tunnelling microscope tip and a conducting sample as a rectangular potential barrier of height ϕ (the work function) above the common Fermi energy EF of the two electrodes, and of width d. The applied bias V is small compared with ϕ (eV≪ϕ), so ϕ may be treated as constant over the range of energies that contribute to the current. At zero temperature only electrons within the bias window of width eV near EF can tunnel elastically into empty states on the other side. Take the WKB transmission coefficient for a thick rectangular barrier as T(E)≈e−2κd, with κ=2me(EF+ϕ−E)/ℏ for an electron of energy E.
((a)) Show that, under these conditions, the tunnel current obeys I∝Ve−2κd, with κ evaluated at E=EF.
((b)) Show that κ=0.512ϕ[eV]A˚−1, with ϕ in electronvolts, using me=9.109×10−31kg, ℏ=1.055×10−34Js and e=1.602×10−19C.
((c)) Evaluate κ for a tip-sample pair with an average work function of 4.5eV.