Model the vacuum gap between a scanning tunnelling microscope tip and a conducting…

PHYSICS · Multi-part · Fermi University Physics · Quantum Mechanics · Condensed Matter, Materials & Soft Matter · Crystal structure, bonding and diffraction

Solid State Physics, Ch Seeing atoms: electron and scanning-probe microscopy

Problem

Model the vacuum gap between a scanning tunnelling microscope tip and a conducting sample as a rectangular potential barrier of height ϕ\phi (the work function) above the common Fermi energy EFE_F of the two electrodes, and of width dd. The applied bias VV is small compared with ϕ\phi (eV≪ϕeV\ll\phi), so ϕ\phi may be treated as constant over the range of energies that contribute to the current. At zero temperature only electrons within the bias window of width eVeV near EFE_F can tunnel elastically into empty states on the other side. Take the WKB transmission coefficient for a thick rectangular barrier as T(E)≈e−2κdT(E)\approx e^{-2\kappa d}, with κ=2me(EF+ϕ−E)/ℏ\kappa=\sqrt{2m_e(E_F+\phi-E)}/\hbar for an electron of energy EE. ((a)) Show that, under these conditions, the tunnel current obeys I∝Ve−2κdI\propto Ve^{-2\kappa d}, with κ\kappa evaluated at E=EFE=E_F. ((b)) Show that κ=0.512ϕ[eV] A˚−1\kappa=0.512\sqrt{\phi[\mathrm{eV}]}\ \mathrm{\AA^{-1}}, with ϕ\phi in electronvolts, using me=9.109×10−31 kgm_e=9.109\times10^{-31}\,\mathrm{kg}, ℏ=1.055×10−34 J s\hbar=1.055\times10^{-34}\,\mathrm{J\,s} and e=1.602×10−19 Ce=1.602\times10^{-19}\,\mathrm{C}. ((c)) Evaluate κ\kappa for a tip-sample pair with an average work function of 4.5 eV4.5\,\mathrm{eV}.

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