A materials scientist argues: "Quartz must be ferroelectric

PHYSICS · Subjective · Fermi University Physics · Mathematical Methods for Physics · Condensed Matter, Materials & Soft Matter · Dielectric and optical properties of solids

Solid State Physics, Ch Dielectric response, local fields and ferroelectricity

Problem

A materials scientist argues: "Quartz must be ferroelectric, since it is well known to be piezoelectric, and any piezoelectric crystal is ferroelectric by definition. Also, the Kramers-Kronig relations are a purely mathematical identity between the real and imaginary parts of any complex function of frequency, so they hold for any ε(ω)\varepsilon(\omega) without needing any physical input." Quartz belongs to point group 3232 (D3D_3 in Schoenflies notation). Evaluate both parts of the claim.

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