An electron (spin one-half) is trapped at a point defect in a crystal

PHYSICS · Multi-part · Fermi University Physics · Mathematical Methods for Physics · Quantum Mechanics · Symmetry, angular momentum and spin

The Structure of Quantum Mechanics, Ch Symmetries, generators and conservation laws

Problem

An electron (spin one-half) is trapped at a point defect in a crystal. The local electrostatic potential energy V(r⃗)V(\vec r) at the defect is real and time-independent and has no rotational symmetry, no reflection symmetry and no inversion symmetry: its only exact symmetry operation is the identity. No magnetic field is present. As a model of a coupling between the electron's motion and its spin, take H^=p^22m+V(r⃗^)+λ p^xS^z,\hat H=\frac{\hat p^2}{2m}+V(\hat{\vec r})+\lambda\,\hat p_x\hat S_z, where λ\lambda is a real constant. ((a)) Using the procedure for reading a degeneracy off a symmetry group, what multiplet dimension does the spatial symmetry of V(r⃗)V(\vec r) alone predict for a generic orbital energy level? State the group. ((b)) Set λ=0\lambda=0 for a moment. Show that every level of H^\hat H is then at least two-fold degenerate without using time reversal, and name the symmetry responsible. ((c)) Now take λ≠0\lambda\neq0. Which components of S^⃗\vec{\hat S} still commute with H^\hat H? Explain why the symmetry they generate forces no degeneracy. ((d)) Show that Θ^\hat\Theta still commutes with H^\hat H when λ≠0\lambda\neq0. State Θ^2\hat\Theta^2 for a spin one-half particle, and use the Kramers argument to find the minimum degeneracy of every level. ((e)) A colleague claims that, because the defect has no spatial symmetry at all, a suitably shaped V(r⃗)V(\vec r) and a suitable λ\lambda could split every level completely. Say what is wrong with this claim, and state what kind of term would lift the degeneracy found in part (d).

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