A nucleus of spin is coupled to the spin of an unpaired electron,
PHYSICS · Subjective · Fermi University Physics · Quantum Mechanics · Symmetry, angular momentum and spin · Symmetry, angular momentum and spin
The Structure of Quantum Mechanics, Ch Adding angular momenta, tensor operators and Wigner-Eckart
Problem
A nucleus of spin j1=23 is coupled to the spin of an unpaired electron, j2=21. Treat this purely as the addition of two angular momenta, with the uncoupled basis ∣m1⟩∣m2⟩ (m1=23,21,−21,−23; m2=21,−21) and the coupled basis ∣J,M⟩. Recall the ladder eigenvalue J^−∣j,m⟩=ℏj(j+1)−m(m−1)∣j,m−1⟩, and that J^−=J^1−+J^2− on the product space. (a) By tabulating M=m1+m2 for all eight product states and peeling multiplets off from the top, derive the decomposition j1⊗j2=⨁JJ for this pair. Check that ∑J(2J+1) equals the dimension of the product space. (b) Starting from the unique top state ∣J=2,M=2⟩=∣m1=23⟩∣m2=21⟩, apply J^− once to write ∣2,1⟩ as a combination of the two product states with M=1. Then use orthogonality inside that two-dimensional M=1 subspace, fixing the sign by the Condon-Shortley convention that the coefficient of ∣m1=23⟩∣m2=−21⟩ is positive, to construct ∣J=1,M=1⟩.