PHYSICS · Multi-part · Fermi University Physics · Thermal, Statistical & Complex Systems · Kinetic theory and transport in gases · Kinetic theory and transport in gases
Thermal Physics, Ch Temperature, pressure and the kinetic theory of gases
Problem
The oxygen in a room (M=32.0gmol−1) is at T=300K. Treat it as a dilute ideal gas with the Maxwell-Boltzmann speed distribution.
((a)) Find the most probable speed vp.
((b)) Estimate the fraction of the molecules with speeds between 390 and 400ms−1, treating f(v) as constant across that narrow range.
((c)) The fraction of molecules faster than v=xvp is π2xe−x2+π2∫x∞e−u2du. Using the tabulated value ∫1∞e−u2du=0.1394, find the fraction of the molecules faster than vp and the fraction slower. Does the peak of the curve split the molecules into two equal halves? Use kB=1.381×10−23JK−1 and NA=6.022×1023mol−1.