PHYSICS · Multi-part · Fermi University Physics · Thermal, Statistical & Complex Systems · Kinetic theory and transport in gases · Kinetic theory and transport in gases
Thermal Physics, Ch Collisions, mean free path and transport in gases
Problem
A vessel holds nitrogen gas (14N2, molecular mass 28.0u) at a pressure of 250Pa and a temperature of 320K. The gas is ideal. A hole of area 0.050mm2 is opened in the wall; the hole is much smaller than the mean free path, so molecules pass through it one at a time without colliding, and outside the vessel there is a vacuum. Take 1u=1.661×10−27kg.
((a)) Calculate the root-mean-square speed and the mean speed of a molecule in the vessel.
((b)) Calculate the number of molecules leaving through the hole per second.
((c)) The vessel is emptied and refilled with a mixture containing equal numbers of 14N2 (28.0u) and 15N2 (30.0u) at the same pressure and temperature. Find the ratio of the rate at which 14N2 molecules leave to the rate at which 15N2 molecules leave.