An air-standard Otto cycle works on of a diatomic ideal gas with constant heat capacities

PHYSICS · Multi-part · Fermi University Physics · Thermal, Statistical & Complex Systems · The laws of thermodynamics · The laws of thermodynamics

Thermal Physics, Ch The second law, entropy and irreversibility

Problem

An air-standard Otto cycle works on 0.0200 mol0.0200\,\mathrm{mol} of a diatomic ideal gas with constant heat capacities, CV=52nRC_V = \tfrac52 nR and γ=7/5\gamma = 7/5. The compression ratio is r=V1/V2=8.00r = V_1/V_2 = 8.00. The four legs are: 1→21 \to 2: reversible adiabatic compression from T1=300 KT_1 = 300\,\mathrm{K}; 2→32 \to 3: constant-volume heating in which 400 J400\,\mathrm{J} of heat is delivered to the gas from a combustion-gas source at 1900 K1900\,\mathrm{K}; 3→43 \to 4: reversible adiabatic expansion back to the volume V1V_1; 4→14 \to 1: constant-volume cooling, the gas being put in thermal contact with the atmosphere, a reservoir at 300 K300\,\mathrm{K}, until it is back at state 1. Take R=8.314 J mol−1 K−1R = 8.314\,\mathrm{J\,mol^{-1}\,K^{-1}} and treat the atmosphere at 300 K300\,\mathrm{K} as the coldest body available. ((a)) Find T2T_2, T3T_3 and T4T_4. ((b)) Find the heat rejected on 4→14 \to 1 and the efficiency of the cycle. ((c)) Find the efficiency of a reversible engine working between the highest and lowest temperatures the gas reaches. ((d)) Draw up the entropy ledger for the leg 4→14 \to 1 (gas column, reservoir column) and give the entropy created per cycle. ((e)) Find the lost work per cycle on that leg. ((f)) Evaluate the sum of Q/TQ/T round the whole cycle, using the temperature of the body that supplies or receives each heat, and check the Clausius inequality.

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