Argon, treated as an ideal gas, is compressed isothermally at a fixed temperature of…

PHYSICS · Multi-part · Fermi University Physics · Thermal, Statistical & Complex Systems · Thermodynamic potentials and the formal structure of thermodynamics · Thermodynamic potentials and the formal structure of thermodynamics

Thermal Physics, Ch Chemical potential, open systems and chemical equilibrium

Problem

Argon, treated as an ideal gas, is compressed isothermally at a fixed temperature of 350 K350\,\mathrm{K} from a pressure of 1.00 bar1.00\,\mathrm{bar} to a pressure of 5.00 bar5.00\,\mathrm{bar}. ((a)) By how much does the chemical potential of the argon change, per molecule? ((b)) Express the same change per mole, in kJ mol−1\mathrm{kJ\,mol^{-1}}. Take kB=1.381×10−23 J K−1k_B = 1.381\times10^{-23}\,\mathrm{J\,K^{-1}}, R=8.314 J mol−1 K−1R = 8.314\,\mathrm{J\,mol^{-1}\,K^{-1}} and NA=6.022×1023 mol−1N_A = 6.022\times10^{23}\,\mathrm{mol^{-1}}.

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