Path Integral and the Schrödinger Equation

By 1948 quantum mechanics already had two complete languages — Heisenberg's matrices and Schrödinger's wave equation — and they were known to be equivalent. Feynman then wrote down a third, seemingly unrelated, starting point: assign every conceivable trajectory from xix_i to xfx_f the phase eiS[x]/ℏe^{iS[x]/\hbar}, where S=∫L dtS=\int L\,\mathrm{d}t is the classical action, and add them all up. The amplitude is a sum over histories. Nothing about that prescription looks like a differential equation for a wavefunction. So the honest question is: does "add phases over paths" actually reproduce Schrödinger's iℏ ∂tψ=H^ψi\hbar\,\partial_t\psi=\hat H\psi, term for term — the kinetic operator, the potential, the factor of ii, everything? It does, and the proof is one of the most instructive short calculations in the subject. The whole argument lives in a single infinitesimal time step. Because the evolution operator e−iH^T/ℏe^{-i\hat H T/\hbar} factorizes into a product of tiny slices, all the physics is hidden in the short-time kernel KεK_\varepsilon. Over an interval ε→0\varepsilon\to0 only trajectories near the straight line contribute, the action collapses to a simple function of the displacement, and KεK_\varepsilon becomes a sharp Gaussian in that displacement times a potential phase. You are ready for this because you already command the Schrödinger equation, Gaussian integrals, and the propagator as a matrix element of the evolution operator. Here we run the machine in reverse: propagate ψ\psi by one short-time kernel, Taylor-expand the convolution to first order in ε\varepsilon, and watch the Gaussian moments turn into spatial derivatives. The second moment builds the kinetic term; the linear-in-ε\varepsilon phase builds the potential; the ε0\varepsilon^0 term fixes the normalization. Out drops the Schrödinger equation, exactly — the closing of the loop that makes the path integral a genuine formulation of quantum mechanics rather than a mnemonic.

Key takeaways
  • The path integral K=∫Dx eiS/ℏK=\int\mathcal D x\,e^{iS/\hbar} and the Schrödinger equation must agree; this article proves the agreement from the short-time kernel.
  • Slicing e−iH^T/ℏe^{-i\hat H T/\hbar} into NN factors reduces everything to Kε(x,y)=A eim(x−y)2/2ℏε e−iεV(x)/ℏK_\varepsilon(x,y)=A\,e^{i m(x-y)^2/2\hbar\varepsilon}\,e^{-i\varepsilon V(x)/\hbar} with A=m/2πiℏεA=\sqrt{m/2\pi i\hbar\varepsilon}.
  • Propagating ψ\psi by one slice and expanding to O(ε)O(\varepsilon) uses just three Gaussian moments: ⟨1⟩=1\langle1\rangle=1, ⟨η⟩=0\langle\eta\rangle=0, ⟨η2⟩=iℏε/m\langle\eta^2\rangle=i\hbar\varepsilon/m.
  • The ⟨η2⟩\langle\eta^2\rangle moment builds the kinetic operator −(ℏ2/2m)∂x2-(\hbar^2/2m)\partial_x^2; the phase e−iεV/ℏe^{-i\varepsilon V/\hbar} builds VV; the ε0\varepsilon^0 term fixes AA.
  • The result is iℏ ∂tψ=−(ℏ2/2m)∂x2ψ+Vψi\hbar\,\partial_t\psi=-(\hbar^2/2m)\partial_x^2\psi+V\psi — the Schrödinger equation, recovered term by term.
  • The dominant paths have (Δx)2∼ε(\Delta x)^2\sim\varepsilon, so Δx/Δt→∞\Delta x/\Delta t\to\infty: quantum paths are continuous but nowhere differentiable, the Wiener signature.
  • Key idea: the entire Schrödinger equation is encoded in one infinitesimal path-integral step — the second Gaussian moment ⟨η2⟩=iℏε/m\langle\eta^2\rangle=i\hbar\varepsilon/m becomes the kinetic operator, and the potential phase becomes VV.
The core insight

Evolving the wavefunction by a single short-time path-integral kernel and expanding the convolution to first order in ε\varepsilon converts the Gaussian moment ⟨η2⟩=iℏε/m\langle\eta^2\rangle=i\hbar\varepsilon/m into the kinetic operator and the potential phase into VV, reproducing the Schrödinger equation exactly.

Where this lives today

The short-time-kernel argument is not just a consistency check; it is the template for how every path integral is defined and simulated. Lattice quantum field theory discretizes spacetime into slices exactly as here, replaces eiS/ℏe^{iS/\hbar} by its Euclidean weight, and integrates the resulting high-dimensional Gaussian-plus-interaction numerically by Monte Carlo — the backbone of modern lattice QCD calculations of hadron masses. In quantum computing, the same Trotter slicing that underlies equation (3) is the standard way to compile a Hamiltonian H^\hat H into a sequence of short-time gates e−iH^εe^{-i\hat H\varepsilon}; the error you make truncating at O(ε2)O(\varepsilon^2) is precisely the term we dropped in Step 2. Whenever someone "Trotterizes" a simulation, they are running Feynman's 1948 calculation forward instead of backward.

The physical picture

Picture evolving ψ\psi one tiny step ε\varepsilon at a time. The short-time kernel is a bell-shaped Gaussian centred on x=yx=y with width ℏε/m\sqrt{\hbar\varepsilon/m} — but a Gaussian with an imaginary variance. Convolving ψ\psi with it is like applying a diffusion operator with an imaginary diffusion constant, and that single ii is what turns ordinary spreading into the wavelike ∂tψ∼i ∂x2ψ\partial_t\psi\sim i\,\partial_x^2\psi of free quantum motion. The kinetic energy is not written into the kernel as a term; it is hidden in the shape of the Gaussian, and it emerges only when you ask how the kernel reshapes ψ\psi over its width.

Figure
One short-time step: a narrow Gaussian smears ψ, and the potential adds a phase
The short-time kernel Kε acting on ψ over one step ε x width √(ℏε/m) Kε(x,y) ∝ exp(i m η²/2ℏε) × e^(−iεV/ℏ) potential = pure phase, first order in ε only y within √(ℏε/m) of x contributes

The potential does its job in a completely different way. It enters as a pure phase e−iV(x)ε/ℏ≈1−iVε/ℏe^{-iV(x)\varepsilon/\hbar}\approx 1-iV\varepsilon/\hbar — first order in ε\varepsilon, zeroth order in derivatives. So kinetic energy and potential energy, which sit on the same footing in H^=p^2/2m+V\hat H=\hat p^2/2m+V, arise from utterly different parts of the kernel: one from the second moment of the Gaussian, the other from a scalar phase. Seeing that asymmetry is the whole content of the calculation, and it is why the derivation is worth doing by hand once.

Figure
The three moments that do all the work
Three Gaussian moments assemble the Schrödinger equation ⟨1⟩ = 1 fixes A = √(m/2πiℏε) the ε⁰ term ⟨η²⟩ = iℏε/m builds kinetic −(ℏ²/2m)∂ₓ² second moment e^(−iεV/ℏ) builds potential + V ψ linear phase

Because the relevant displacements scale as Δx∼ε\Delta x\sim\sqrt{\varepsilon}, the trajectories that dominate have velocity Δx/Δt∼1/ε→∞\Delta x/\Delta t\sim 1/\sqrt{\varepsilon}\to\infty: continuous but nowhere differentiable, exactly the analytic character of Brownian (Wiener) motion rotated to real time. The Schrödinger equation is, in this light, the imaginary-diffusion-constant cousin of the heat equation — an observation we make precise in Imaginary-Time and Euclidean Path Integrals.

The core equations

Everything rests on two statements that must be shown to agree. The first is the path-integral definition of the propagator, the amplitude to travel from one spacetime point to another; the second is its operator definition. We pin the conventions here and use them throughout: the action is S=∫L dtS=\int L\,\mathrm{d}t with L=12mx˙2−V(x)L=\tfrac12 m\dot x^2-V(x), and the free propagator carries the prefactor m/2πiℏt\sqrt{m/2\pi i\hbar t}.

K(xf,tf;xi,ti)=∫D[x(t)]  e iS[x(t)]/ℏ,S=∫titf ⁣(12mx˙2−V)dt(1)K(x_f,t_f;x_i,t_i)=\int\mathcal D[x(t)]\;e^{\,iS[x(t)]/\hbar},\qquad S=\int_{t_i}^{t_f}\!\Big(\tfrac12 m\dot x^2-V\Big)\mathrm{d}t \qquad (1)

where: KK — the propagator, i.e. the transition amplitude from (xi,ti)(x_i,t_i) to (xf,tf)(x_f,t_f); SS — classical action along a path; LL — Lagrangian; D[x]\mathcal D[x] — the functional measure summing over all paths with fixed endpoints. Physically, the construction of this object from time-slicing is owned by The Feynman Path Integral Formulation; here we take it as given and ask what differential law it obeys. The operator definition is the anchor that ties KK to ordinary quantum mechanics. It is the position matrix element of the evolution operator.

K(xf,tf;xi,ti)=⟨xf∣ e−iH^(tf−ti)/ℏ ∣xi⟩,H^=p^22m+V(2)K(x_f,t_f;x_i,t_i)=\langle x_f|\,e^{-i\hat H (t_f-t_i)/\hbar}\,|x_i\rangle,\qquad \hat H=\frac{\hat p^2}{2m}+V \qquad (2)

where: H^\hat H — Hamiltonian; ℏ\hbar — reduced Planck constant. Reading it physically: KK is the kernel that propagates any state, ψ(xf,tf)=∫K ψ(xi,ti) dxi\psi(x_f,t_f)=\int K\,\psi(x_i,t_i)\,\mathrm dx_i — the property established in The Propagator from Path Integrals — so if we can find the equation KK satisfies over an infinitesimal step, we have found the equation ψ\psi satisfies. The short-time kernel is where the two definitions meet. For a single slice ε\varepsilon, equation (1) has only the straight-line path to leading order, and equation (2) is expanded to first order in ε\varepsilon; both give the same Gaussian.

Kε(x,y)=m2πiℏε  exp⁡ ⁣[im(x−y)22ℏε]  exp⁡ ⁣[−iεV(x)ℏ](3)K_\varepsilon(x,y)=\sqrt{\frac{m}{2\pi i\hbar\varepsilon}}\;\exp\!\Big[\frac{i m (x-y)^2}{2\hbar\varepsilon}\Big]\;\exp\!\Big[-\frac{i\varepsilon V(x)}{\hbar}\Big] \qquad (3)

where: x−y=ηx-y=\eta is the displacement in one slice; the first exponential is the free (kinetic) part, the second the potential phase. The normalization m/2πiℏε\sqrt{m/2\pi i\hbar\varepsilon} is not an input — it is fixed by demanding ∫Kε dy=1+O(ε)\int K_\varepsilon\,\mathrm dy=1+O(\varepsilon), i.e. that a static wavefunction stays normalized. That self-consistency is the ε0\varepsilon^0 moment below.

Derivation AThe three Gaussian moments of the short-time kernel

Our goal is the three integrals that carry the entire calculation: the zeroth moment (which fixes the normalization AA), the first moment (which vanishes by symmetry), and the second moment (which will become the kinetic operator). The subtlety is that the Gaussian is oscillatory — its variance is imaginary — so the integrals are Fresnel integrals, evaluated by analytic continuation of the ordinary Gaussian formula. We keep the endpoint xx fixed and integrate over the displacement η=y−x\eta=y-x, using the shorthand a=m/2ℏεa=m/2\hbar\varepsilon.

Step 1. Write the free-kernel weight as w(η)=A eiaη2w(\eta)=A\,e^{i a\eta^2} with A=m/2πiℏεA=\sqrt{m/2\pi i\hbar\varepsilon} and a=m/2ℏεa=m/2\hbar\varepsilon. Why: stripping the potential phase (which multiplies everything by a constant e−iεV/ℏe^{-i\varepsilon V/\hbar} handled separately) isolates the pure Gaussian in the displacement.

Step 2. Zeroth moment. The Fresnel integral ∫−∞∞eiaη2dη=π/a eiπ/4=iπ/a\int_{-\infty}^{\infty}e^{i a\eta^2}\mathrm d\eta=\sqrt{\pi/a}\,e^{i\pi/4}=\sqrt{i\pi/a}, so A ⁣∫eiaη2dη=1A\!\int e^{i a\eta^2}\mathrm d\eta=1. Why: this is exactly the condition that fixes AA; the eiπ/4e^{i\pi/4} Fresnel phase is what supplies the i\sqrt i in the denominator of AA, so the normalization is consistent, not imposed twice.

Step 3. First moment. ⟨η⟩=A ⁣∫η eiaη2dη=0\langle\eta\rangle=A\!\int\eta\,e^{ia\eta^2}\mathrm d\eta=0 because the integrand is odd. Why: no drift — the kernel is symmetric about x=yx=y, so to leading order it neither pushes ψ\psi left nor right; the physics is pure spreading.

Step 4. Second moment. Differentiating the Fresnel integral with respect to the parameter gives ⟨η2⟩=A ⁣∫η2eiaη2dη=i2a=iℏεm\langle\eta^2\rangle=A\!\int\eta^2 e^{ia\eta^2}\mathrm d\eta=\dfrac{i}{2a}=\dfrac{i\hbar\varepsilon}{m}. Why: this single imaginary number is the seed of the entire kinetic operator. Its magnitude ℏε/m\hbar\varepsilon/m is the mean-square displacement per step (the Wiener scaling ⟨η2⟩∼ε\langle\eta^2\rangle\sim\varepsilon), and its phase ii is what will make the kinetic term appear with the right factor of ii.

Go deeper · Derivation B · 1 minAssembling the Schrödinger equation at order ε
Derivation BAssembling the Schrödinger equation at order ε

Now we propagate the wavefunction by one slice and match powers of ε\varepsilon. The strategy: substitute the short-time kernel into ψ(x,t+ε)=∫Kε(x,y)ψ(y,t) dy\psi(x,t+\varepsilon)=\int K_\varepsilon(x,y)\psi(y,t)\,\mathrm dy, Taylor-expand ψ(y)\psi(y) around xx and the potential phase in ε\varepsilon, then use the three moments. Watch that the η2\eta^2 moment is itself O(ε)O(\varepsilon), so a second-derivative term survives at first order even though it looks higher order.

Step 1. Substitute and expand: with η=y−x\eta=y-x, ψ(y)=ψ+η ψx+12η2ψxx+⋯\psi(y)=\psi+\eta\,\psi_x+\tfrac12\eta^2\psi_{xx}+\cdots and e−iεV/ℏ=1−iεV/ℏ+⋯e^{-i\varepsilon V/\hbar}=1-i\varepsilon V/\hbar+\cdots, so

ψ(x,t+ε)=(1−iεVℏ)[⟨1⟩ψ+⟨η⟩ψx+12⟨η2⟩ψxx]+O(ε2).\psi(x,t+\varepsilon)=\Big(1-\tfrac{i\varepsilon V}{\hbar}\Big)\Big[\langle1\rangle\psi+\langle\eta\rangle\psi_x+\tfrac12\langle\eta^2\rangle\psi_{xx}\Big]+O(\varepsilon^2).

Why: the Gaussian kills the odd term and weights the even terms by their moments; the potential factors out because V(x)V(x) is evaluated at the fixed endpoint.

Step 2. Insert the moments ⟨1⟩=1, ⟨η⟩=0, ⟨η2⟩=iℏε/m\langle1\rangle=1,\ \langle\eta\rangle=0,\ \langle\eta^2\rangle=i\hbar\varepsilon/m:

ψ(x,t+ε)=(1−iεVℏ)[ψ+iℏε2mψxx]+O(ε2)=ψ+ε[iℏ2mψxx−iℏVψ]+O(ε2).\psi(x,t+\varepsilon)=\Big(1-\tfrac{i\varepsilon V}{\hbar}\Big)\Big[\psi+\tfrac{i\hbar\varepsilon}{2m}\psi_{xx}\Big]+O(\varepsilon^2)=\psi+\varepsilon\Big[\tfrac{i\hbar}{2m}\psi_{xx}-\tfrac{i}{\hbar}V\psi\Big]+O(\varepsilon^2).

Why: the ε0\varepsilon^0 term reproduces ψ\psi (consistency), and the cross term (iεV/ℏ)(iℏε/2m)ψxx(i\varepsilon V/\hbar)(i\hbar\varepsilon/2m)\psi_{xx} is O(ε2)O(\varepsilon^2) and dropped.

Step 3. Match to ψ(x,t+ε)=ψ+ε ψt+O(ε2)\psi(x,t+\varepsilon)=\psi+\varepsilon\,\psi_t+O(\varepsilon^2) and read off the O(ε1)O(\varepsilon^1) coefficient:

ψt=iℏ2mψxx−iℏVψ.\psi_t=\frac{i\hbar}{2m}\psi_{xx}-\frac{i}{\hbar}V\psi.

Why: the left side is just the definition of the time derivative; equating first-order terms is the whole matching.

Step 4. Multiply by iℏi\hbar:

iℏ ∂ψ∂t=−ℏ22m∂2ψ∂x2+Vψ.i\hbar\,\frac{\partial\psi}{\partial t}=-\frac{\hbar^2}{2m}\frac{\partial^2\psi}{\partial x^2}+V\psi.

Why: the kinetic operator carries the sign and factor set entirely by ⟨η2⟩\langle\eta^2\rangle; the potential is the scalar phase. The Schrödinger equation has appeared with no extra assumptions.

Limiting cases

caseresultmeaning
V=0V=0free short-time kernel, ⟨η2⟩=iℏε/m\langle\eta^2\rangle=i\hbar\varepsilon/m onlypure diffusion with imaginary constant → free Schrödinger equation
ℏ→0\hbar\to0Gaussian width ℏε/m→0\sqrt{\hbar\varepsilon/m}\to0kernel collapses to the classical straight-line path; stationary phase (see Stationary Phase and the Classical Limit)
t→−iτt\to-i\tau⟨η2⟩→ℏε/m\langle\eta^2\rangle\to\hbar\varepsilon/m (real)imaginary-time rotation turns the wave kernel into the real diffusion (heat) kernel
finite TTcomposition of NN slicesthe one-step equation guarantees the full-time evolution by concatenation

Worked examples

Example 1 — the second moment, numerically. Compute ⟨η2⟩\langle\eta^2\rangle for the short-time kernel with m=1m=1, ℏ=1\hbar=1, and slice ε=0.01\varepsilon=0.01 (natural units), and confirm it is the seed of the kinetic term.

Step 1. The moment formula from the derivation is ⟨η2⟩=iℏε/m\langle\eta^2\rangle=i\hbar\varepsilon/m.

Step 2. Substitute: ⟨η2⟩=i (1)(0.01)/(1)=0.01 i\langle\eta^2\rangle=i\,(1)(0.01)/(1)=\mathbf{0.01\,i}.

Step 3. Interpret. The mean-square displacement per step is ∣⟨η2⟩∣=0.01|\langle\eta^2\rangle|=0.01, so the typical hop is 0.01=0.1\sqrt{0.01}=0.1 — the Wiener scaling ℏε/m\sqrt{\hbar\varepsilon/m}. The pure imaginary value is what makes the kinetic operator iℏ2m⟨η2⟩/ε⋅∂x2=iℏ2m⋅iℏm∂x2\tfrac{i\hbar}{2m}\langle\eta^2\rangle/\varepsilon\cdot\partial_x^2=\tfrac{i\hbar}{2m}\cdot\tfrac{i\hbar}{m}\partial_x^2… wait, more directly: the coefficient of ψxx\psi_{xx} in ψt\psi_t is 12⟨η2⟩/ε=12(iℏ/m)=iℏ/2m\tfrac12\langle\eta^2\rangle/\varepsilon=\tfrac12(i\hbar/m)=i\hbar/2m, giving after ×iℏ\times i\hbar the term −ℏ2/2m-\hbar^2/2m. The single number 0.01i0.01i carries the sign, the factor ii, and the magnitude of the kinetic operator.

Example 2 — assembling the operator by hand. Show that the three parts of the short-time kernel map onto the three pieces of H^ψ\hat H\psi and confirm the term-by-term correspondence for a definite potential, say V(x)=12mω2x2V(x)=\tfrac12 m\omega^2 x^2.

Step 1. The ε0\varepsilon^0 piece: ⟨1⟩ψ=ψ\langle1\rangle\psi=\psi. This is the identity — it says ψ\psi does not change at zeroth order, and it fixed A=m/2πiℏεA=\sqrt{m/2\pi i\hbar\varepsilon}.

Step 2. The ⟨η2⟩\langle\eta^2\rangle piece: 12⟨η2⟩ψxx=12(iℏε/m)ψxx\tfrac12\langle\eta^2\rangle\psi_{xx}=\tfrac12(i\hbar\varepsilon/m)\psi_{xx}. Dividing by ε\varepsilon and multiplying by iℏi\hbar gives −ℏ22mψxx-\tfrac{\hbar^2}{2m}\psi_{xx} — the kinetic operator.

Step 3. The potential-phase piece: −iεVℏψ=−iεℏ(12mω2x2)ψ-\tfrac{i\varepsilon V}{\hbar}\psi=-\tfrac{i\varepsilon}{\hbar}\big(\tfrac12 m\omega^2 x^2\big)\psi. Dividing by ε\varepsilon and multiplying by iℏi\hbar gives +12mω2x2 ψ=Vψ+\tfrac12 m\omega^2 x^2\,\psi=V\psi — the potential operator, here the oscillator potential.

Step 4. Sum. iℏψt=−ℏ22mψxx+12mω2x2ψi\hbar\psi_t=-\tfrac{\hbar^2}{2m}\psi_{xx}+\tfrac12 m\omega^2 x^2\psi — the oscillator Schrödinger equation, reconstructed entirely from the short-time path-integral kernel. Every piece of H^\hat H has a distinct kernel origin: identity → ε0\varepsilon^0, kinetic → second moment, potential → linear phase.

Origins · 1 minclassical action and how this was discovered
CA
classical action
central object S = ∫L dt · The action functional whose stationary value gives the classical trajectory (Hamilton's principle) and whose exponential e^{iS/ℏ} weights each path in Feynman's sum over histories — the bridge from the Lagrangian world to quantum amplitudes

The classical action is the object this whole formulation is built on: Hamilton's principle δS=0\delta S=0 picks the classical path, and Feynman's insight was that quantum mechanics keeps all paths but weights them by eiS/ℏe^{iS/\hbar}. In the derivation above, SS appears in the short-time kernel as mη2/2εm\eta^2/2\varepsilon (the free part) minus εV\varepsilon V (the potential part) — the discretized action of a single slice. That the Schrödinger equation drops out of summing these phases is the precise statement that "extremize SS classically" and "sum eiS/ℏe^{iS/\hbar} quantumly" are two faces of one dynamics.

History
1923
— Wiener constructs a rigorous measure on continuous, nowhere-differentiable paths — the imaginary-time ancestor of the path integral
1933
— Dirac notes that e^{iS/ℏ} "corresponds to" the quantum transformation function over short times
1942
— Feynman's Princeton thesis recasts quantum mechanics as a sum over spacetime histories
1948
— Feynman publishes the path integral and proves its equivalence to the Schrödinger equation by exactly this short-time argument
1949
— Kac turns the imaginary-time version into the rigorous Feynman-Kac formula

Going further

This article closes the loop opened by The Feynman Path Integral Formulation: that article builds the propagator K=∫Dx eiS/ℏK=\int\mathcal D x\,e^{iS/\hbar} from time-slicing; here we show the same KK, applied over one slice, satisfies the Schrödinger equation. The kernel's role as the object that evolves ψ\psi is owned by The Propagator from Path Integrals, and the historical Feynman-vs-Schrödinger story is told in the Time-Dependent Schrödinger Equation. The imaginary-time rotation flagged in the limiting-cases table is developed in Imaginary-Time and Euclidean Path Integrals, and the ℏ→0\hbar\to0 collapse to the classical path is taken up by Stationary Phase and the Classical Limit.

Prerequisites. Lagrangian and Hamiltonian mechanics · the Time-Dependent Schrödinger Equation · Gaussian integrals and moments · The Quantum Propagator. Leads to. Imaginary-Time and Euclidean Path Integrals · Stationary Phase and the Classical Limit · lattice field theory.

Why is the second moment imaginary while an ordinary diffusion variance is real?

Because the exponent of the free kernel is imη2/2ℏεim\eta^2/2\hbar\varepsilon, not −η2/2σ2-\eta^2/2\sigma^2. The variance is σ2→iℏε/m\sigma^2\to i\hbar\varepsilon/m, an imaginary "diffusion constant." That single factor of ii is the difference between a heat equation (real diffusion, spreading probability) and the Schrödinger equation (imaginary diffusion, spreading amplitude with interference). Rotate time to t=−iτt=-i\tau and the ii disappears — you get genuine diffusion, which is exactly the Euclidean path integral.

Why can I Taylor-expand ψ(y) but not the potential's spatial dependence?

You expand ψ(y)\psi(y) around xx because the Gaussian confines yy to within ℏε/m\sqrt{\hbar\varepsilon/m} of xx, so only a few derivatives of ψ\psi survive at each order in ε\varepsilon. The potential is evaluated at the fixed endpoint xx (a standard mid-point/endpoint prescription for a smooth VV); the difference V(y)−V(x)V(y)-V(x) is O(η)O(\eta), and multiplied by the already-O(ε)O(\varepsilon) potential phase it is O(ε3/2)O(\varepsilon^{3/2}) — beyond the order we keep. For singular potentials the ordering prescription matters and must be handled with care.

Doesn't a second-derivative term look like it should be higher order than first order in ε?

It would be, if ⟨η2⟩\langle\eta^2\rangle were O(1)O(1). But it is O(ε)O(\varepsilon): ⟨η2⟩=iℏε/m\langle\eta^2\rangle=i\hbar\varepsilon/m. So 12⟨η2⟩ψxx\tfrac12\langle\eta^2\rangle\psi_{xx} is genuinely first order in ε\varepsilon even though it carries two spatial derivatives. This is the crux of the calculation and the reason a naive power counting fails: in the path integral, one factor of ε\varepsilon "costs" two factors of Δx\Delta x, the Wiener scaling (Δx)2∼ε(\Delta x)^2\sim\varepsilon.

Where does the factor of i in front of ∂ₜψ actually come from?

From the second moment. The coefficient of ψxx\psi_{xx} in ψt\psi_t is 12⟨η2⟩/ε=iℏ/2m\tfrac12\langle\eta^2\rangle/\varepsilon=i\hbar/2m, which is imaginary. Multiplying through by iℏi\hbar to clear it produces iℏ ψti\hbar\,\psi_t on the left and the real operator −ℏ2/2m ψxx-\hbar^2/2m\,\psi_{xx} on the right. So the ii multiplying the time derivative is inherited directly from the imaginary variance of the free kernel — no separate assumption of complex time evolution is needed.

Is this derivation exact, or only leading order?

The equation it derives is exact — the Schrödinger equation is recovered with no approximation. What is "leading order" is the single-slice kernel: it agrees with the true short-time propagator only to O(ε)O(\varepsilon), with O(ε2)O(\varepsilon^2) corrections (operator-ordering and V2V^2 terms). But the differential equation lives at O(ε1)O(\varepsilon^1), and the neglected O(ε2)O(\varepsilon^2) terms vanish in the continuum limit ε→0\varepsilon\to0. This is exactly the Trotter error in Hamiltonian simulation, controlled by taking more, thinner slices.

How does this relate to the operator-ordering ambiguity in quantum mechanics?

The endpoint at which you evaluate VV (initial point, final point, or midpoint) corresponds to different operator orderings of p^\hat p and x^\hat x in H^\hat H. For a potential V(x)V(x) with no momentum dependence, all choices agree at O(ε)O(\varepsilon) and give the same Schrödinger equation. For Hamiltonians with xx-dependent kinetic terms (a curved configuration space, or p f(x) pp\,f(x)\,p) the choice does not drop out, and the path integral must be defined with a specific ordering — the midpoint (Weyl) prescription is the standard one. This subtlety is invisible for the ordinary p^2/2m+V\hat p^2/2m+V treated here.

Why call the paths "Brownian" if there is no randomness in quantum mechanics?

The analogy is analytic, not probabilistic. Quantum paths and Brownian paths share the same short-distance scaling ⟨(Δx)2⟩∝Δt\langle(\Delta x)^2\rangle\propto\Delta t, so both are continuous and nowhere differentiable, and both are described by a Gaussian short-time kernel. The difference is the factor of ii: Brownian motion has a real, positive transition density (a genuine probability), while the quantum kernel is complex and interferes. Wick-rotating time turns the quantum path integral into a true Wiener (Brownian) integral, which is why Wiener's 1923 measure is the rigorous foundation of the Euclidean theory.

Before this

Where this leads