ARCHETYPE: Photoelectric-Effect Numericals
Hand an examiner one photocell, one metal and one lamp, and they can mint a dozen different questions from it: find the work function from a threshold wavelength, the stopping potential from a colour of light, the maximum electron speed, the metal's identity from two data points, the number of electrons a milliwatt beam kicks out per second. Every one of them is the same physics — Einstein's one-line equation, energy in equals energy to escape plus energy left over — dressed in different exam clothes. Learn the machine once and the whole family becomes fill-in-the-blanks. This is a numerical gym, so the bookkeeping is the article. At its centre sits the equation you met in the concept article: a photon of frequency carries energy ; it spends the work function prising one electron off the surface, and whatever is left over becomes the electron's maximum kinetic energy, . Stop those fastest electrons with a reverse voltage and that voltage — the stopping potential — reads the leftover energy directly, because . Three symbols, one straight line, and every photoelectric numerical on CBSE, ICSE, JEE, NEET, AP Physics 2 and A-Level 9702 falls out of it. The trap that costs half the class its marks is a single confusion: brightness versus colour. Intensity sets how many electrons come out (the current); frequency sets how fast they come out (the stopping potential). Keep those two channels separate, carry the photon shortcut on the tip of your pen, and the questions turn from feared to routine. This article drills the master recipe and the variants examiners actually pose, with every number computed to the last digit.
- The engine of every photoelectric numerical is Einstein's equation : photon energy in, work function spent, kinetic energy left over.
- The stopping potential reads the leftover energy directly: , so numerically in volts equals in electronvolts.
- Use the photon shortcut — a 200 nm photon is eV, a 400 nm photon is eV — and never touch and separately unless the question forces SI.
- Threshold is where the leftover runs out: , nm. Below (above ) nothing comes out, however bright the lamp.
- Two colours give two stopping potentials, and the slope of the -versus- line is V·s — this is exactly how Millikan measured Planck's constant.
- Intensity sets the current, frequency sets the energy — the saturation current counts electrons, the stopping potential clocks their speed.
- Key idea: one equation, , plus the threshold and the slope , solve the entire photoelectric numerical family — provided you never let a brighter lamp change the electron energy.
Every photoelectric numerical reduces to Einstein's energy balance : the photon energy (or in eV) minus the work function gives the maximum kinetic energy, which the stopping potential measures directly; threshold is where that leftover vanishes () and the -versus- slope is the constant .
Where this lives today
The arithmetic you just drilled is the operating manual for a whole industry of light detectors. Every photomultiplier tube — the workhorse of medical PET scanners, particle-physics calorimeters and night-vision optics — begins with a photocathode obeying , and engineers choose its material by exactly the work-function-versus-threshold logic of example 2: a low- alkali cathode to catch visible light, a wider-gap material to see only the ultraviolet. Solar-cell physicists run the same threshold calculation for the band gap that sets which colours a panel can harvest. Photoelectron spectroscopy — the standard tool for reading the electronic structure of surfaces and catalysts — is quite literally the two-colour method of example 3 turned into a measuring instrument: shine monochromatic light of known energy, measure the electrons' kinetic energy, and read off the binding energies inside the material. The stopping-potential graph Millikan drew in 1916 is now printed on the calibration certificate of instruments in every surface-science lab in the world.
The setup
Bookkeeping first, because in a numerical gym the accounting is the physics. Light of frequency falls on a clean metal surface whose electrons are held in by a binding energy — the work function, the minimum energy needed to lift the least-bound electron out through the surface. In the photon picture the light arrives in indivisible lumps of energy , and one electron absorbs one whole lump. That electron must first pay to escape; if the lump is smaller than nothing happens, and if it is larger, the surplus rides out with the electron as kinetic energy. The most energetic electrons — the ones that were least tightly bound and lose nothing extra on the way out — carry
where: — the maximum kinetic energy of the ejected photoelectrons; — the energy of one photon ( J·s is Planck's constant); — the work function of the metal. Read it as a cash-flow statement: income , fixed cost , profit . If income falls below the fixed cost the electron never leaves. To measure you do not chase the electrons with a stopwatch — you stop them with a voltage. Make the collector plate negative so it repels the electrons; wind the voltage up until even the fastest electron is turned back and the current just falls to zero. That critical voltage is the stopping potential , and the work done against it exactly drains the fastest electron's kinetic energy:
where: — the stopping (cut-off) potential; C — the electron charge. Because energy in electronvolts is charge-times-volts by definition, equation (2) has a gift built in: measured in volts is numerically equal to in electronvolts. A leftover of eV means a stopping potential of exactly V. That is why exam problems and this gym live in electronvolts — the arithmetic is almost done before you start.
The master relations
Three tools run the entire family. The first is the photon energy in exam-friendly units. Starting from and folding in , and , the product comes out as eV·nm to three figures, so
where: — the photon energy in electronvolts; — the wavelength in nanometres. This single line replaces three constants: a nm photon is eV, a nm photon is eV, a nm (red) photon is eV. Commit to memory and most board problems need no calculator gymnastics at all. The second tool is the threshold, the boundary where the leftover falls to zero. Setting in equation (1) gives the threshold frequency, and translating to wavelength with equation (3):
where: — the threshold (cut-off) frequency; — the threshold wavelength. Photons below (equivalently, wavelengths longer than ) cannot free a single electron no matter how intense the beam. For caesium ( eV) the threshold is nm — yellow light works, red does not; for tungsten ( eV) it is a deep-ultraviolet nm. Note the inverse: a bigger work function means a shorter threshold wavelength. The third tool is the straight line. Rearranging equation (2) as is the equation of a line in the variables and : gradient , horizontal intercept at , vertical intercept at .
where: the slope is a universal constant, the same for every metal — only the intercepts move as the metal changes. This is the deepest single fact in the topic: measure the slope of anyone's -versus- graph and you have measured Planck's constant. Millikan did exactly this in 1916.
The variants examiners actually pose
Find the work function. Given a threshold wavelength , invert equation (4): eV. Given instead a stopping potential at a known wavelength, rearrange equation (2): (with in volts read as eV). Both are one line of algebra.
Find the stopping potential. The workhorse: , in volts. If the answer comes out negative or zero, the light is below threshold and no electrons are emitted — a favourite trick.
Find Planck's constant (two-colour method). Shine two different wavelengths, measure two stopping potentials, and take the slope: . Multiply by to recover . The work function drops out of the difference, so you get without ever knowing .
Count the electrons (power and efficiency). Intensity questions live in a separate channel. A beam of power at wavelength delivers photons per second; a fraction (the quantum efficiency) eject electrons, giving photoelectrons per second, and a saturation current . Notice: this branch uses the photon energy only to count photons — it never touches or , because how many electrons come out has nothing to do with how fast they go.
The goal is to turn the three given quantities of almost every photoelectric problem — a wavelength , a work function , and the constants — into the stopping potential , and to see exactly where each input enters so the recipe can be run backwards for any unknown. The strategy is pure energy bookkeeping and algebra: no calculus, no differential equations, just Einstein's one-line balance rearranged. Watch the units travel: electronvolts throughout, so the final volts fall out for free.
Step 1. Convert the light to photon energy. One photon of wavelength carries , which in exam units is eV by equation (3). For nm this is eV.
Step 2. Subtract the escape cost. By equation (1) the fastest electron keeps . For tungsten, eV, so eV. If this were negative you would stop here and report "no emission".
Step 3. Read the leftover as a voltage. Equation (2) says , and because one electronvolt is one electron-charge times one volt, the number of electronvolts of kinetic energy equals the number of volts of stopping potential: V.
Step 4. Run it backwards for any unknown. Given and , the same chain gives . Given and , it gives . The recipe is one equation solved for whichever letter the question hides. Verified: eV, eV and V are recomputed independently in verify_hs2-photoelectric-numericals.py.
Go deeper · Derivation B · 1 minThe two-colour slope method: measuring Planck's constant without knowing the work function
The goal is Millikan's trick — extract (and, as a bonus, ) from two stopping-potential measurements at two wavelengths, without ever being told the metal's work function. The strategy is to write Einstein's equation twice and subtract: the unknown is the same in both, so it cancels, leaving a clean ratio. This is algebra of simultaneous equations, nothing more.
Step 1. Write equation (2) at each frequency: and , with . Take caesium lit first by nm ( Hz) then by nm ( Hz).
Step 2. Subtract to kill : . The work function has vanished — the difference of two stopping potentials depends only on the difference of frequencies and on .
Step 3. Solve for the slope. . With the measured V and V, the slope is V·s.
Step 4. Recover the constants. Multiply by : J·s — Planck's constant, to within a per cent of the accepted , from nothing but two voltmeter readings. Back-substitute one point to get eV, identifying the metal as caesium. Verified: the slope V·s, the recovered J·s and eV are recomputed in verify_hs2-photoelectric-numericals.py.
Trap table and limiting cases
| pitfall or limiting case | what actually happens | the fix |
|---|---|---|
| brighter light, faster electrons? | no — intensity raises the current, not | frequency sets energy, intensity sets number |
| (below threshold) | zero emission, however intense | check before computing |
| exactly | , | electrons just barely escape with no speed |
| depends on the metal? | the value does; the slope does not | only intercepts move between metals |
| using and separately | slow and error-prone | use |
| eV versus joule | in volts in eV numerically | multiply by only when SI joules are wanted |
| very small (hard UV/X-ray) | , work function negligible | at high energy is a tiny correction |
Worked examples
1 · Board level — the master template (CBSE and NEET pattern)
Ultraviolet light of wavelength nm falls on a clean tungsten surface of work function eV. Find the energy of each photon, the maximum kinetic energy of the emitted electrons, and the stopping potential.
Step 1. Photon energy by the shortcut, equation (3): .
Step 2. Subtract the work function, equation (1): . It is positive, so electrons are emitted.
Step 3. The stopping potential reads the leftover directly, equation (2): , so .
Step 4. Sense-check: the photon (6.2 eV) comfortably clears the 4.5 eV barrier, and nm is well below tungsten's threshold nm, so emission is expected. Everything consistent.
2 · Board level — threshold, and does the light even work (ICSE and CBSE pattern)
Caesium has a work function of eV. Find its threshold wavelength and threshold frequency. Then decide whether nm violet light ejects electrons, and if so give the stopping potential.
Step 1. Threshold wavelength, equation (4): (yellow-green).
Step 2. Threshold frequency, equation (4): .
Step 3. Test the nm light: its photon energy is eV, which exceeds eV — and nm is shorter than nm — so electrons are emitted.
Step 4. Stopping potential: eV, so . Note that a red nm photon ( eV) would be below threshold and eject nothing.
3 · Competitive level — measure Planck's constant from two colours (JEE-Advanced and A-Level pattern)
A photocell records a stopping potential of V under nm light and V under nm light. From these two data points alone, find Planck's constant and the work function of the cathode.
Step 1. Convert to frequencies: Hz; Hz.
Step 2. The work function cancels in the difference of two Einstein equations, leaving the slope: V·s.
Step 3. Recover Planck's constant: , within of the accepted .
Step 4. Recover the work function from either point: , so the cathode is caesium. Timing note: about 90 seconds. The whole method is "write it twice and subtract" — the moment you see that cancels, only the slope remains, and there is no need to solve for the work function first.
4 · Competitive level — count the electrons and the saturation current (JEE-Main and A-Level pattern)
A mW beam of nm light strikes a photocathode of quantum efficiency (one electron per twenty incident photons). How many photoelectrons are emitted per second, and what saturation current do they carry?
Step 1. Energy of one photon in joules: eV eV J.
Step 2. Photons arriving per second: photons per second.
Step 3. Photoelectrons per second at efficiency: .
Step 4. Saturation current, A . Timing note: about 60 seconds. This branch never touches or — the photon energy is used only to count photons. Doubling the beam power would double the current and leave the stopping potential untouched, the whole point of the intensity channel.
Exam traps
Confusing intensity with frequency. Intensity sets how many electrons (the saturation current); frequency sets how fast (the stopping potential). Turning up the lamp never raises . This is the single biggest mark-loser in the topic; state which channel each number lives in before you compute.
Forgetting to check threshold. Always confirm (equivalently ) before writing a stopping potential. If the photon energy is below the work function, the answer is "no emission", not a negative . Examiners plant sub-threshold light precisely to catch the automatic subtracter.
Splitting and when you needn't. For energies, is faster and less error-prone than juggling , and . Reserve the SI constants for when the question explicitly wants joules or frequency.
Mixing electronvolts and joules. in volts equals in electronvolts — do not multiply by a second time. Convert to joules only when the current or an SI energy is asked for. A stray factor of (or ) is an instant order-of-magnitude blunder.
Unit slips on wavelength and power. Keep nanometres in the shortcut, but convert to metres for , and milliwatts to watts for photon counting. Carry four significant figures through the working and present two or three.
Board scope. Photoelectric numericals are firmly examined on CBSE, ICSE, JEE-Main, JEE-Advanced and NEET, and also on AP Physics 2 (the Modern Physics unit) and A-Level 9702, which both do stopping-potential and threshold problems and the slope. IB Physics carries the photoelectric equation at Higher Level only and does not set it as a numerical-drill objective, and IGCSE 0625 has no photoelectric content at all — do not revise this lane for an IGCSE paper.
Origins · 1 minRobert Millikan and how this was discovered
Robert Andrews Millikan was the American experimentalist who nailed down two of the numbers this whole gym runs on. His 1909–1913 oil-drop experiment measured the electron's charge — the very constant that turns a stopping potential into an energy — to a then-unmatched precision. He then turned, sceptically, to Einstein's 1905 photoelectric equation, which he frankly disbelieved; he spent a decade building meticulous vacuum photocells to disprove it. Instead his stopping-potential-versus-frequency graphs came out dead straight, and in 1916 he read Planck's constant off their slope, , confirming Einstein's quantum picture to about half a per cent. It is a model of science overruling a scientist's prejudice by measurement. Millikan received the Nobel Prize in Physics in 1923 for the elementary charge and the photoelectric effect, and later ran the California Institute of Technology into a research powerhouse. Every slope method in this article is his.
Going further
Texts. NCERT Physics Class 12, Ch. 11 ("Dual Nature of Radiation and Matter"), the photoelectric sections and exercises · H. C. Verma, Concepts of Physics Vol. 2, "Photoelectric Effect and Wave–Particle Duality," worked problems · D. C. Pandey / Irodov photoelectric problem sets (for the two-colour slope and photon-count variants) · Cambridge A-Level 9702, quantum-physics stopping-potential problems.
Provenance. Standard exam-archive problems. Recompute: master template nm on W () eV, eV, V; caesium () threshold nm, Hz; nm on Cs eV, V; two-colour ( and nm, and V) slope V·s, J·s, eV; photon count ( mW, nm, ) photons/s, electrons/s, A; photon references eV, eV; slope constant V·s.
Prerequisites. Einstein's Photoelectric Equation — the concept article that derives and the – line this gym uses. Leads to. the university seam The Photoelectric Effect and the Photon (`aq-qm-photoelectric-effect-photon`), which develops the quantum picture and the photon momentum in full.
Go deeper (UG). The rigorous quantum-mechanical account — the photon as a quantum of the electromagnetic field, the exact energy distribution of photoelectrons, and the tunnelling and band-structure corrections to the simple work function — is developed in The Photoelectric Effect and the Photon. Enrichment only; nothing here depends on it.
Why is the stopping potential in volts numerically equal to the kinetic energy in electronvolts?
Because of how the electronvolt is defined. One electronvolt is the energy an electron gains crossing a potential difference of one volt: . The stopping condition is , so if you measure in electronvolts, the on both sides cancels and the number of electronvolts equals the number of volts. A leftover kinetic energy of eV is stopped by exactly V. This is not a coincidence or an approximation — it is built into the units, and it is why every photoelectric problem is easiest in electronvolts. Convert to joules only if a question asks for an SI energy or a current, where in joules is .
How do I know whether any electrons are emitted at all?
Check the photon energy against the work function before you do anything else. Compute eV and compare with . If (equivalently, if the wavelength is shorter than the threshold ), electrons come out and . If , no electrons are emitted, however intense the light, and the correct answer is "zero photocurrent", not a negative stopping potential. Examiners deliberately set light just below threshold to catch students who subtract on autopilot and report an impossible negative . Making this one-line check your first step turns those trick questions into free marks.
The two-colour method gives h without the work function — how can that be?
Because subtraction erases the work function. Write Einstein's equation at each frequency: and . The same sits in both — it is a property of the metal, not of the light — so when you subtract one equation from the other, the terms cancel and you are left with . The slope of the line therefore carries and nothing about the metal. This is exactly why the -versus- graph has the same gradient for caesium, sodium and tungsten: only the intercepts, which do contain , differ. If you later want , substitute either data point back into a single Einstein equation.
What is the difference between saturation current and stopping potential in a numerical?
They live in two independent channels, and mixing them is the classic error. The saturation current is the maximum photocurrent, reached when the collector is positive enough to gather every ejected electron; its size is set by how many electrons are emitted per second, which is set by the light's intensity (through the photon-counting formula ). The stopping potential is the reverse voltage that just halts the fastest electron; its size is set by how fast the electrons are, which is set by the light's frequency (through ). Intensity moves the saturation plateau up and down; frequency slides the stopping potential left and right. A single question often gives you data for both — keep them in separate columns.
Which value of Planck's constant and which shortcut should I use in exams?
Use J·s eV·s, m/s and C — the standard board values. For photon energies the shortcut saves time and error; it is just rounded to eV·nm. When you need a frequency, use in SI (metres). The one place the two shortcuts can disagree at the third digit is a two-colour slope, where the energy shortcut and the frequency route are rounded differently — that is why example 3's slope comes out rather than exactly ; both are "Planck's constant to two figures". Quote the value your board's data sheet prints, and keep four figures in the working.
Is this gym the same as the concept article on Einstein's photoelectric equation?
It shares the physics but not the purpose. The concept article derives the equation — why light must be quantised, why there is a threshold, why classical waves fail — and explains the meaning of every term. This article assumes all that and drills using it fast and correctly under exam time: the master solve, the threshold check, the two-colour slope, the photon count. Think of the concept article as the theory lecture and this as the problem class. If a formula here feels unmotivated, revisit the concept article; if you understand the physics but keep losing marks to intensity-versus-frequency slips or forgotten threshold checks, this gym is where you fix them.