Dispersion and radiation

Hold a glass prism up to sunlight and a single beam of "white" light fans out into a full rainbow. That split happens because glass does not treat every colour the same way — each wavelength bends by a different amount because each one sees a slightly different refractive index. This spreading with wavelength is called dispersion, and it forces a small but important correction to how fast a wave packet of light actually travels through a medium: the phase fronts and the energy-carrying envelope no longer move at the same speed. This article also answers a second, seemingly unrelated question that turns out to share the same physical root — electromagnetic waves themselves. Why does an electric charge radiate light at all? The answer is a single word: acceleration. Together, dispersion and radiation close out the electromagnetic-waves story of this block — one governs how light of different colours propagates once it exists, the other explains where light comes from in the first place.

The core insight

A medium's refractive index depends on wavelength, n(λ)n(\lambda), which splits phase velocity vp=c/nv_p=c/n from group velocity vg=c/(n−λ dn/dλ)v_g=c/(n-\lambda\,dn/d\lambda) — this is dispersion — while electromagnetic radiation is emitted only by an accelerating charge, never by one at rest or moving at constant velocity.

The core idea

Why a prism splits colours. In vacuum every wavelength of light travels at the same speed cc. Inside a real medium this is no longer true: the refractive index nn is a function of wavelength, n(λ)n(\lambda), and the phase velocity is

vp=cn(λ).v_p=\frac{c}{n(\lambda)}.

where: vpv_p is the phase velocity of a single wavelength inside the medium, cc is the vacuum speed of light, and n(λ)n(\lambda) is the refractive index at that wavelength. Because nn is different for red and violet light, each colour bends by a different angle on refraction, and a prism fans white light into a spectrum.

Normal versus anomalous dispersion. Over most of the visible range, transparent materials have nn decreasing as λ\lambda increases — violet bends more than red. This everyday behaviour is called normal dispersion, and it is well approximated by Cauchy's empirical relation n(λ)=A+B/λ2n(\lambda)=A+B/\lambda^2, away from any absorption band. Very close to a natural absorption resonance of the material, the trend reverses sharply over a narrow band of wavelengths — nn rises steeply with λ\lambda there instead — and this reversal is called anomalous dispersion. It is "anomalous" only in sign, not in the sense of being absent; it is actually the strongest wavelength dependence a material shows, concentrated right where it absorbs.

Figure
A prism splitting a white beam into a fan of colours from violet bending most to red bending least
Dispersion in a prism — each wavelength sees a different n white light violet, n large red, n small Violet sees a higher n than red, so it bends more — normal dispersion

Radiation from accelerating charges. A charge sitting still produces only a static electric field; a charge moving at constant velocity (a steady current) produces only a static magnetic field — neither one radiates any energy outward. Radiation begins only when a charge accelerates: its fields can no longer keep up instantaneously, so a disturbance detaches and propagates outward as a self-sustaining electromagnetic wave, a changing E⃗\vec E generating a B⃗\vec B and vice versa, travelling at speed cc. An oscillating charge — an electron shaking in a dipole antenna, or in an atom — is the qualitative picture of dipole radiation: it radiates in all directions except along its own axis of oscillation, at the same frequency as its motion. This is the physical origin of every electromagnetic wave discussed in this block, including visible light itself.

Derivation AGroup velocity in a dispersive medium

The goal is to show that when a medium's refractive index depends on wavelength, the speed at which a wave packet's energy travels, the group velocity vg=dω/dkv_g=d\omega/dk, differs from the phase velocity vp=c/nv_p=c/n, and to reduce that difference to one compact working formula in terms of n(λ)n(\lambda) and dn/dλdn/d\lambda that can be evaluated from a single measured slope.

Step 1. Start from the definitions carried over from the wave-packet chapter: phase velocity vp=ω/kv_p=\omega/k and group velocity vg=dω/dkv_g=d\omega/dk. Inside the medium, vp=c/n(λ)v_p=c/n(\lambda), so ω=kvp=kcn\omega=kv_p=\dfrac{kc}{n}, with nn itself depending on kk (equivalently on λ\lambda) whenever the medium is dispersive.

Step 2. Differentiate ω=kc/n\omega=kc/n with respect to kk using the product/quotient rule, treating nn as a function of kk:

vg=dωdk=cn−kcn2dndk.v_g=\frac{d\omega}{dk}=\frac{c}{n}-\frac{kc}{n^2}\frac{dn}{dk}.

The first term alone would just give back vpv_p; the second term is the correction from nn changing with kk, and it vanishes exactly when the medium is non-dispersive.

Step 3. Convert the derivative from kk to the more commonly tabulated λ\lambda. Since k=2π/λk=2\pi/\lambda, the chain rule gives dn/dk=−λ22πdndλdn/dk=-\dfrac{\lambda^2}{2\pi}\dfrac{dn}{d\lambda}. Substituting this and k=2π/λk=2\pi/\lambda into Step 2 and simplifying the algebra collapses the expression to

vg=cn−λ dndλ.v_g=\frac{c}{n-\lambda\,\dfrac{dn}{d\lambda}}.

where: nn is the refractive index at the wavelength of interest and dn/dλdn/d\lambda is the slope of the dispersion curve there, obtained from a fit like Cauchy's relation or from tabulated data.

Step 4. Check the limits. If the medium is non-dispersive, dn/dλ=0dn/d\lambda=0 and the formula correctly reduces to vg=vp=c/nv_g=v_p=c/n. If the medium is normally dispersive, dn/dλ<0dn/d\lambda<0, so the denominator n−λ dn/dλn-\lambda\,dn/d\lambda exceeds nn, giving vg<vpv_g<v_p: the wave packet's envelope — the energy and information it carries — lags slightly behind its own phase fronts.

Worked example

A glass has refractive index n=1.520n=1.520 at the sodium D line, λ=589 nm\lambda=589\ \text{nm}, with a measured slope dn/dλ=−4.30×104 m−1dn/d\lambda=-4.30\times10^4\ \text{m}^{-1} there (a typical crown-glass value; the derivative carries units of m−1^{-1} because λ\lambda is measured in metres). Find vpv_p and vgv_g at this wavelength.

Step 1. Phase velocity: vp=cn=3×1081.520=1.974×108 m/sv_p=\dfrac{c}{n}=\dfrac{3\times10^8}{1.520}=1.974\times10^8\ \text{m/s}.

Step 2. Evaluate the group-velocity denominator: n−λdndλ=1.520−(589×10−9)(−4.30×104)=1.520+0.02533=1.545n-\lambda\dfrac{dn}{d\lambda}=1.520-(589\times10^{-9})(-4.30\times10^4)=1.520+0.02533=1.545.

Step 3. Group velocity: vg=c1.545=3×1081.545=1.942×108 m/sv_g=\dfrac{c}{1.545}=\dfrac{3\times10^8}{1.545}=1.942\times10^8\ \text{m/s}. As expected for normal dispersion (dn/dλ<0dn/d\lambda<0), vg<vpv_g<v_p: here vgv_g is about 1.6%1.6\% slower than vpv_p, confirming the wave packet's envelope lags slightly behind its phase fronts. vp=1.974×108 m/sv_p=1.974\times10^8\ \text{m/s} and vg=1.942×108 m/sv_g=1.942\times10^8\ \text{m/s}.

Competitive stretch

A material follows Cauchy's formula n(λ)=1.50+6.0×10−15 m2λ2n(\lambda)=1.50+\dfrac{6.0\times10^{-15}\ \text{m}^2}{\lambda^2} over the visible range. At λ=400 nm\lambda=400\ \text{nm} (violet), n=1.50+6.0×10−15(4.0×10−7)2=1.50+0.0375=1.5375n=1.50+\dfrac{6.0\times10^{-15}}{(4.0\times10^{-7})^2}=1.50+0.0375=1.5375. At λ=700 nm\lambda=700\ \text{nm} (red), n=1.50+6.0×10−15(7.0×10−7)2=1.50+0.01224=1.5122n=1.50+\dfrac{6.0\times10^{-15}}{(7.0\times10^{-7})^2}=1.50+0.01224=1.5122. Since dn/dλ=−2×6.0×10−15λ3<0dn/d\lambda=-\dfrac{2\times6.0\times10^{-15}}{\lambda^3}<0 everywhere, this is normal dispersion throughout the visible range, and nviolet=1.5375>nred=1.5122n_{\text{violet}}=1.5375>n_{\text{red}}=1.5122 confirms violet bends more than red — the everyday prism result.

Common traps

  • Assuming dispersion always means vg>vpv_g>v_p — the sign is set by dn/dλdn/d\lambda; in ordinary normal dispersion, vg<vpv_g<v_p.
  • Treating anomalous dispersion as "no dispersion" — it is a stronger, reversed-sign effect near an absorption band, not the absence of wavelength dependence.
  • Thinking a moving charge always radiates — a charge at rest or moving at constant velocity does not radiate; only acceleration produces radiation.
  • Reaching for the full Larmor power formula — only the qualitative picture (accelerating charge implies radiation) is in scope here; the quantitative radiated-power law is beyond this course.

Ask the tutor: Want the full step-by-step vg=dω/dk→vg=c/(n−λ dn/dλ)v_g=d\omega/dk\to v_g=c/(n-\lambda\,dn/d\lambda) algebra spelled out, or the radiation picture tied more precisely to Maxwell's equations? Ask the AI tutor to walk through either one.

If phase velocity and group velocity are different, which one is the speed of light I actually measure with a stopwatch and a light source

Group velocity is the one that matches everyday measurement, because it is the speed of the envelope of a wave packet — the pulse of energy and information a real light source sends out. Phase velocity describes how the individual crests inside that packet slide along, which can differ from the envelope's speed once the medium is dispersive. In a non-dispersive medium the two coincide, so the distinction only matters once dn/dλ≠0dn/d\lambda\neq0.

Why does a prism spread white light into a rainbow but a flat glass window does not visibly do so

Both the prism and the window have the same wavelength-dependent n(λ)n(\lambda), so both bend violet slightly more than red at each surface. In a flat window the two parallel faces bend the ray back by equal and opposite amounts, so the colours recombine into one white beam on exit, just shifted sideways. A prism's two faces are not parallel, so the second bending adds to the first instead of cancelling it, and the small angular differences between colours accumulate into a visible fan.

Why can't a charge moving at constant velocity radiate, even though it still has electric and magnetic fields around it

Its fields are not zero, but they are unchanging in the charge's own frame and simply translate rigidly along with it — nothing detaches to travel independently through space. Radiation requires the fields at a point to keep changing in time in a way that outruns the charge itself, which only happens when the charge's velocity itself is changing, i.e. when it accelerates. A steady current or a charge cruising at constant speed produces only the static-field pattern appropriate to that motion, carried along, not radiated away.

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Where this leads