Newton's law of cooling

A cup of tea at 80∘C80^\circ\text{C} left in a 30∘C30^\circ\text{C} room does not cool at a steady rate. It plunges fast in the first few minutes, then dawdles as it nears room temperature, and mathematically never quite gets there. Newton's law of cooling captures this everyday fact: the rate of heat loss depends on how far above the surroundings a body is, not on its temperature in isolation. Twice the temperature excess means twice the cooling rate. This is the closing topic of the Heat transfer section in Unit 8, "Heat and Thermodynamics," coming right after conduction, convection, and the radiation laws. The syllabus is explicit that deriving the law from Stefan's law is not required — you need the statement, the graph, and the ability to crunch numericals, in both the instantaneous and the average-temperature forms. Below, the core proportionality is set up, its most exam-useful average-interval form is derived, and both are applied to worked numbers so you can see exactly how a cooling curve flattens as it approaches room temperature.

The core insight

The rate of cooling of a body is directly proportional to the excess of its temperature over the surroundings, −dTdt=k(T−Ts)-\frac{dT}{dt} = k(T-T_s), so cooling is fast when hot and slows to a crawl as T→TsT \to T_s.

The core idea

  • The statement. A body loses heat — and its temperature falls — at a rate proportional to the temperature difference between the body and its surroundings, provided that difference stays small.
  • Why "small" matters. Real heat loss (conduction, convection, radiation combined) is a more complicated function of temperature; Newton's law is the linear approximation that holds only when the body is not drastically hotter than its surroundings.
  • The shape of the curve. Plotted against time, temperature falls steeply at first and flattens as it approaches TsT_s, giving an exponential-decay-like curve that never crosses below TsT_s.
  • Where it sits among the other heat-transfer laws. Conduction and convection carry heat through a medium in contact with the body, while radiation obeys Stefan's law with a T4T^4 dependence; Newton's law of cooling is not a separate physical mechanism but a convenient linear stand-in for the combined effect of all three, valid only when the body is not far above room temperature.

The instantaneous form is:

−dTdt=k(T−Ts)-\frac{dT}{dt} = k(T - T_s)

where: TT is the instantaneous temperature of the body, TsT_s is the constant temperature of the surroundings, tt is time, and kk is a positive cooling constant fixed by the body's surface area, material, and heat capacity. The minus sign on the left just records that TT decreases with time whenever T>TsT > T_s; the law does not fire in reverse to predict overshoot below TsT_s. Because an instantaneous rate is awkward to measure directly, the exam-friendly version replaces it with an average rate over a finite interval, and swaps the instantaneous TT for the average of the initial and final temperatures:

T1−T2t=k(T1+T22−Ts)\frac{T_1 - T_2}{t} = k\left(\frac{T_1 + T_2}{2} - T_s\right)

where: T1T_1 and T2T_2 are the temperatures at the start and end of an interval of duration tt, and T1+T22\frac{T_1+T_2}{2} stands in for "the temperature during the interval." This approximation is only good when T1−T2T_1 - T_2 is small, which is exactly the regime the law is meant for.

Figure
Cooling curve of temperature against time starting steep near eighty degrees and flattening as it approaches a dashed surroundings line at thirty degrees
Cooling curve: steep start, flat finish time t temperature T surroundings T_s = 30 C 80 C at t = 0 slope shrinks as T falls
Derivation AThe average-interval form of Newton's law

Starting from the instantaneous proportionality −dTdt=k(T−Ts)-\frac{dT}{dt} = k(T-T_s), show why replacing the exact rate over a short cooling interval with the average rate T1−T2t\frac{T_1-T_2}{t} and the instantaneous temperature with the average T1+T22\frac{T_1+T_2}{2} gives an equation that is accurate enough for numericals whenever the temperature drop in that interval is small.

Step 1. Treat the interval from T1T_1 to T2T_2 (occurring over time tt) as short enough that kk and TsT_s can be taken as constant throughout — this is guaranteed by the same "small temperature difference" condition the law already requires.

Step 2. Over this short interval, the average rate of temperature fall is simply the total drop divided by the total time, T1−T2t\frac{T_1-T_2}{t}, which approximates −dTdt-\frac{dT}{dt} evaluated somewhere inside the interval rather than at a single instant.

Step 3. Since k(T−Ts)k(T-T_s) varies only slightly across the interval (because T1−T2T_1-T_2 is small), its value at the midpoint temperature is a good stand-in for its average value across the whole interval — so k(T−Ts)k(T-T_s) is replaced by k(T1+T22−Ts)k\left(\frac{T_1+T_2}{2}-T_s\right).

Step 4. Equating the two approximations gives the working formula T1−T2t=k(T1+T22−Ts)\frac{T_1-T_2}{t} = k\left(\frac{T_1+T_2}{2}-T_s\right), which lets you compute kk from one measured interval and then predict tt or a temperature for a second interval, exactly as required by the syllabus.

Worked example

A liquid cools from 80∘C80^\circ\text{C} to 70∘C70^\circ\text{C} in 5 minutes in surroundings at 30∘C30^\circ\text{C}. Find the time taken to cool further from 70∘C70^\circ\text{C} to 60∘C60^\circ\text{C}.

Step 1. For the first interval, T1=80T_1 = 80, T2=70T_2 = 70, t1=5 mint_1 = 5\ \text{min}, and the average temperature is 80+702=75∘C\frac{80+70}{2} = 75^\circ\text{C}.

Step 2. Substitute into the average-interval form to find kk:

80−705=k(75−30)  ⟹  2=45k  ⟹  k=245 min−1\frac{80-70}{5} = k(75-30) \implies 2 = 45k \implies k = \frac{2}{45}\ \text{min}^{-1}

Step 3. For the second interval, T1=70T_1 = 70, T2=60T_2 = 60, average temperature =65∘C= 65^\circ\text{C}, and the same kk applies since the liquid and surroundings are unchanged:

10t2=245(65−30)=245(35)=7045≈1.556 ∘C/min\frac{10}{t_2} = \frac{2}{45}(65-30) = \frac{2}{45}(35) = \frac{70}{45} \approx 1.556\ ^\circ\text{C/min}

Step 4. Solve for t2t_2:

t2=101.556≈6.43 minutest_2 = \frac{10}{1.556} \approx \mathbf{6.43\ minutes}

The second 10-degree drop takes noticeably longer than the first (6.43 min versus 5 min) — direct confirmation that cooling slows as the liquid approaches room temperature.

Competitive stretch

Using the same k=245 min−1k = \frac{2}{45}\ \text{min}^{-1}, estimate the instantaneous rate of cooling right at t=0t=0, when the liquid is at 80∘C80^\circ\text{C}. Using −dTdt=k(T−Ts)=245(80−30)=245(50)≈2.22 ∘C/min-\frac{dT}{dt} = k(T-T_s) = \frac{2}{45}(80-30) = \frac{2}{45}(50) \approx 2.22\ ^\circ\text{C/min}. Compare this to the average rate found over the first interval, 105=2 ∘C/min\frac{10}{5}=2\ ^\circ\text{C/min} — the instantaneous rate at the start of the interval is slightly higher than the interval average, exactly as expected since the rate is falling throughout the interval. This also shows why the average-interval formula is only an approximation: it quietly smooths out the fact that the true rate keeps changing even within a single 5-minute window, which is fine as long as the temperature drop within that window stays small.

Common traps

  • Applying the law when the temperature excess is large — it is only a good approximation for small (T−Ts)(T-T_s); for big differences, the true T4T^4 radiative dependence takes over and the linear law fails.
  • Using T1T_1 (the starting temperature) instead of the average T1+T22\frac{T_1+T_2}{2} in the interval form — this is the single most common numerical slip.
  • Assuming TsT_s can change during the process — the law only holds for a fixed surrounding temperature.
  • Treating kk as a universal constant — it depends on the specific body's shape, surface, and material, and must be found from given data, not recalled from memory.
  • Mixing up which temperature is which in the interval formula — T1T_1 is always the earlier (hotter) reading and T2T_2 the later (cooler) one, so T1−T2T_1-T_2 and the average T1+T22\frac{T_1+T_2}{2} must be computed in that order every time.

Ask the tutor: Stuck on a two-interval cooling problem or unsure which temperature to average — walk through your own numbers with the AI tutor.

Why does the tea cool fast at first and slowly later, even though no heat is being added

Because the cooling rate itself depends on the temperature excess (T−Ts)(T-T_s), not on some fixed rate of heat loss. When the tea is 50∘C50^\circ\text{C} above room temperature, it loses heat quickly; as it approaches room temperature, that excess shrinks, so the loss rate shrinks too. It is the same physical process throughout — only the driving temperature difference is changing, which is exactly what makes the curve steep-then-flat rather than a straight line.

Do I need to derive Newtons law of cooling from Stefans law for the ISC exam

No. The syllabus explicitly says this derivation is not required. You are expected to know the statement of the law, both its instantaneous and average-interval mathematical forms, be able to sketch and read a cooling curve, and solve numericals using the interval form — the connection to the T4T^4 radiation law is background context, not examinable derivation.

Why do we use the average of T1 and T2 instead of just T1 in numerical problems

Because the interval form of the law is an approximation to the instantaneous law over a finite stretch of time, and using the starting temperature T1T_1 throughout would overestimate the cooling rate for the whole interval, since the body is actually cooler than T1T_1 for most of that time. The average T1+T22\frac{T_1+T_2}{2} better represents the "typical" temperature during the interval, which is why it appears in the syllabus formula and in every mark scheme.

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