A solution that is in and in is titrated dropwise with at

CHEMISTRY · Subjective · AP · Chemistry · Equilibrium · Equilibrium

Problem

A solution that is

0.020\,\text{M}

\text{Cl}^-

and

0.020\,\text{M}

\text{I}^-

is titrated dropwise with

0.020\,\text{M}\ \text{Pb(NO}_3)_2

25^{\circ}\text{C}

. The solubility products are

K_{sp}(\text{PbCl}_2)=1.6\times10^{-5}

and

K_{sp}(\text{PbI}_2)=1.4\times10^{-8}

. Which lead halide precipitates first? Briefly justify your answer.