A chemist has 100.0mL of 0.0100MBaCl2 at 25 °C. The solubility-product constant for BaSO4 is 1.1×10−10. Assuming the solution volume remains essentially constant, calculate the minimum mass (in grams) of solid K2SO4 (molar mass 174.3g mol−1) that must be dissolved to begin precipitation of BaSO4.