A chemist mixes 50.0 mL of 1.0 × 10^ −3 M AgNO_3 with 25.0 mL of 4.0 × 10^ −3 M NaCl…

CHEMISTRY · Single correct · CBSE · Chemistry · Equilibrium · Equilibrium

Problem

A chemist mixes 50.0 mL of 1.0 × 10^{−3} M AgNO_3 with 25.0 mL of 4.0 × 10^{−3} M NaCl at 25 °C. The solubility product constant for AgCl at this temperature is K_{sp} = 1.8 × 10^{−10}. Which statement correctly describes the resulting mixture? (a) A precipitate of AgCl\text{AgCl} will form because QQ is less than KspK_{sp}. (b) No precipitate will form because dilution keeps both ion concentrations below the solubility product. (c) A precipitate of AgCl\text{AgCl} will form because QQ exceeds KspK_{sp}. (d) No precipitate will form because the limiting Ag+\text{Ag}^+ is completely used up, making QQ effectively zero.

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