Two different reactions are analyzed using average bond energies

CHEMISTRY · Single correct · A Level · Chemistry · Energetics · Energetics

Problem

Two different reactions are analyzed using average bond energies. For Reaction A, breaking all reactant bonds requires 1640 kJ1640\ \text{kJ}, and forming all product bonds releases 1780 kJ1780\ \text{kJ}. Which statement correctly characterizes Reaction A? (a) Reaction A is endothermic because 1640 kJ1640\,\text{kJ} must be absorbed to break the reactant bonds. (b) Reaction A is endothermic because 1780 kJ−1640 kJ=140 kJ1780\,\text{kJ}-1640\,\text{kJ}=140\,\text{kJ} must be supplied to the system. (c) Reaction A is exothermic because 1780 kJ−1640 kJ=140 kJ1780\,\text{kJ}-1640\,\text{kJ}=140\,\text{kJ} of energy is released overall. (d) Reaction A is endothermic with ΔH=+3420 kJ\Delta H=+3420\,\text{kJ} because energy is absorbed in both bond-breaking and bond-forming steps.

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