A binary compound contains only magnesium and nitrogen

CHEMISTRY · Single correct · AP · Chemistry · Atomic Structure and Properties · Atomic Structure and Properties

Problem

A binary compound contains only magnesium and nitrogen. If an analysis reports that the compound is 60.3 % magnesium by mass, which statement best explains why the mass percentage of nitrogen must be 39.7 %? (a) Because the empirical formula of magnesium nitride is Mg3N2\mathrm{Mg_3N_2}, the compound contains three magnesium atoms for every two nitrogen atoms, so nitrogen’s mass percentage is 25×100%≈39.7%\tfrac{2}{5}\times100\%\approx39.7\%. (b) Because the ratio of the molar masses 24.3:14.024.3:14.0 for Mg:N simplifies to about 60:4060:40, nitrogen must contribute the remaining 39.7%39.7\% of the compound’s mass. (c) Because a compound that consists of exactly two elements must have mass percentages that sum to 100%100\%, so the remaining 39.7%39.7\% must correspond to nitrogen. (d) Because converting 60.3%60.3\% magnesium to moles (60.3/24.360.3/24.3) and then multiplying by nitrogen’s molar mass gives about 39.7%39.7\%, which represents nitrogen’s percent by mass.

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