Two separate laboratory bottles are labeled “carbon monoxide.” • Sample A contains…

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Problem

Two separate laboratory bottles are labeled “carbon monoxide.” • Sample A contains 1.00 g of carbon and 1.33 g of oxygen. • Sample B contains 1.00 g of carbon and 2.66 g of oxygen. Which explanation is most consistent with these data? (a) Both bottles contain carbon monoxide; the apparent doubling of oxygen mass is simply due to different sample sizes, not different compounds. (b) Sample A is more likely carbon dioxide because its oxygen-to-carbon mass ratio is closer to 2:12:1, the ratio in CO2\mathrm{CO_2}.},{ (c) Sample B is more likely carbon dioxide than carbon monoxide because its oxygen-to-carbon mass ratio is exactly double that of Sample A. (d) Both bottles could still be carbon monoxide if Sample B’s oxygen were the heavier isotope 18O^{18}\mathrm{O}, which would double the oxygen mass without changing the formula.

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