When aqueous iron(III) chloride is mixed with aqueous sodium hydroxide

CHEMISTRY · Multi-part · A Level · Chemistry · Amount of substance · Amount of substance

Problem

When aqueous iron(III) chloride is mixed with aqueous sodium hydroxide, an insoluble iron(III) hydroxide precipitate forms according to FeCl3(aq)+3 NaOH(aq)→Fe(OH)3(s)+3 NaCl(aq)\text{FeCl}_3(aq) + 3\,\text{NaOH}(aq) \rightarrow \text{Fe(OH)}_3(s) + 3\,\text{NaCl}(aq) A chemist combines 75.0 mL of 0.250 M FeCl3\text{FeCl}_3 with 125.0 mL of 0.200 M NaOH\text{NaOH}. Assume volumes are additive and the precipitate is completely removed from the mixture. (a) Calculate the initial moles of Fe3+\text{Fe}^{3+} and OH−\text{OH}^- ions present before the reaction occurs. (b) Determine the limiting reactant and justify your choice with appropriate stoichiometric calculations. (c) Compute the mass, in grams, of Fe(OH)3\text{Fe(OH)}_3 that precipitates. (d) After the precipitate is filtered off, calculate the molarity of each ion that remains in the clear filtrate.

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