Given, Select the correct statement :

CHEMISTRY · Single correct · A Level · Chemistry · Thermodynamics · Thermodynamics

Problem

Given, 2Fe2O3(s)⟶4Fe(s)+3O2(g);ΔrG1∘=+1487 kJ mol−12\text{Fe}_2\text{O}_{3(s)} \longrightarrow 4\text{Fe}_{(s)} + 3\text{O}_{2(g)}; \Delta_r G_1^\circ = +1487 \text{ kJ mol}^{-1} 6CO(g)+3O2(g)⟶6CO2(g);ΔrG2∘=−1543.2 kJ mol−16\text{CO}_{(g)} + 3\text{O}_{2(g)} \longrightarrow 6\text{CO}_{2(g)}; \Delta_r G_2^\circ = -1543.2 \text{ kJ mol}^{-1} Select the correct statement : (1) ΔrG∘\Delta_r G^\circ for reduction of iron oxide by CO is +56.2 kJ mol−1+56.2 \text{ kJ mol}^{-1} (2) Fe2O3\text{Fe}_2\text{O}_3 can be reduced by CO spontaneously (3) Fe2O3\text{Fe}_2\text{O}_3 cannot be reduced by CO spontaneously (4) The reduction of Fe2O3\text{Fe}_2\text{O}_3 takes part in higher part of blast furnace.

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