Barium carbonate, BaCO

CHEMISTRY · Multi-part · AP · Chemistry · Equilibrium · Equilibrium

Problem

Barium carbonate, BaCO3_3, is sparingly soluble in water. At 25 °C its solubility–product constant is Ksp=5.1×10−9K_{sp}=5.1\times10^{-9}. A student adds 0.300 g0.300\,\text{g} of BaCO3_3 to 1.00 L1.00\,\text{L} of pure water at 25 °C, seals the container, and stirs until equilibrium is reached. (a) Calculate the molar solubility (in mol L−1^{-1}) of BaCO3_3 at 25 °C. (b) Determine the maximum mass of BaCO3_3 that can dissolve in 1.00 L1.00\,\text{L} of water at 25 °C. (c) Based on your result in part (b), calculate the mass of BaCO3_3 (in grams) that will remain undissolved in the container once equilibrium is established.

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