For the reaction

CHEMISTRY · Single correct · A Level · Chemistry · Thermodynamics · Thermodynamics

Problem

For the reaction A⇌B\text{A}\rightleftharpoons\text{B}, the standard Gibbs free energy change at 298 K298\,\text{K} is ΔG∘=+15.0  kJ mol−1\Delta G^{\circ}=+15.0\;\text{kJ mol}^{-1}. Assuming this value of ΔG∘\Delta G^{\circ} is temperature-independent, calculate the equilibrium constant KK at 350 K350\,\text{K}. (Use R=8.314  J mol−1 K−1R=8.314\;\text{J mol}^{-1}\,\text{K}^{-1}.) (a) 7.6×10−27.6\times10^{-2} (b) 9.9×10−19.9\times10^{-1} (c) 5.8×10−35.8\times10^{-3} (d) 2.3×10−32.3\times10^{-3}

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