A research laboratory isolates of solid elemental sulfur intended to contain exactly atoms

CHEMISTRY · Multi-part · A Level · Chemistry · Amount of substance · Amount of substance

Problem

A research laboratory isolates 0.250 g0.250\,\text{g} of solid elemental sulfur intended to contain exactly 4.70×10214.70 \times 10^{21} atoms. Subsequent mass-spectrometric analysis reveals an actual count of 4.58×10214.58 \times 10^{21} atoms in the sample. The molar mass of sulfur is 32.06 g mol−132.06\,\text{g}\,\text{mol}^{-1}. Answer the following questions, showing all steps clearly. (1) Part 1: a) Using the sample’s measured mass, calculate the theoretical number of sulfur atoms that the 0.250 g0.250\,\text{g} portion should contain. (2) Part 2: b) Determine the percent error between the experimentally measured atom count and the theoretical value from part (a). (3) Part 3: c) Suggest one plausible experimental factor that could account for the observed percent error, and briefly justify your choice based on chemical reasoning.

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