Two hydroxide salts are listed below with their solubility–product constants measured at 25 °C.
Salt
Dissolution Equation
Ksp
Mg(OH)2
Mg(OH)2(s) ⟶ Mg2+ + 2 OH−
5.6×10−12
Ca(OH)2
Ca(OH)2(s) ⟶ Ca2+ + 2 OH−
5.5×10−6
Assume that 100mL of pure water at 25 °C is available for each salt.
(a) Without performing detailed numerical calculations, predict which salt has the greater molar solubility at 25 °C. Justify your prediction based on the information provided.
(b) Taking into account both molar solubility and molar mass considerations, explain which salt is expected to produce the greater mass of dissolved solid in 100mL of water. Support your explanation qualitatively without explicit numerical computation.