Aqueous solutions of barium chloride and sodium sulfate are combined at 25 °C.
• 25.0 mL of 0.040 M BaCl2
• 35.0 mL of 0.060 M Na2SO4
The solubility‐product constant for BaSO4 at this temperature is Ksp=1.1×10−10. Assume volumes are additive.
(a) Calculate the molar concentrations of Ba2+ and SO42− immediately after mixing but before any precipitation occurs.
(b) Determine the ionic product Q for BaSO4 under the conditions in part (a).
(c) State whether a precipitate of BaSO4 will form. Justify your answer by comparing Q to Ksp.
(d) Write the net ionic equation for any reaction that takes place or clearly indicate that no reaction occurs.