To prepare 1.00 L of a buffer that remains at the pKₐ of a monoprotic weak acid HA and can neutralize 0.050 mol of added HCl, a technician may purchase 2.0 M HA at $0.040 per mL and 1.5 M NaA at $0.020 per mL. The total chemical cost must not exceed $2.00. Which purchasing plan satisfies both the capacity requirement and the cost limit?
(a) 25mL of 2.0M HA and 25mL of 1.5M NaA
(b) 35mL of 2.0M HA and 47mL of 1.5M NaA
(c) 25mL of 2.0M HA and 33mL of 1.5M NaA
(d) 25mL of 2.0M HA and 40mL of 1.5M NaA