Standard enthalpies of formation at 298 K (kJ mol ) are as follows: CH (g) = –75, C H…

CHEMISTRY · Subjective · AP · Chemistry · Thermochemistry · Thermochemistry

Problem

Standard enthalpies of formation at 298 K (kJ mol−1^{-1}) are as follows: CH4_4(g) = –75, C2_2H4_4(g) = +52, CO2_2(g) = –394, H2_2O(l) = –286, O2_2(g) = 0. Each hydrocarbon undergoes complete combustion to CO2_2(g) and H2_2O(l). Identify which fuel—CH4_4 or C2_2H4_4—releases the greater amount of energy per mole upon combustion, and state one brief thermodynamic reason based on the data above.

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