Samples of 14 g of N₂(g) and 16 g of CH₄(g) are mixed in a rigid container at 298 K

CHEMISTRY · Single correct · AP · Chemistry · Atomic Structure and Properties · Atomic Structure and Properties

Problem

Samples of 14 g of N₂(g) and 16 g of CH₄(g) are mixed in a rigid container at 298 K. Which statement best describes the average molar mass of the resulting gaseous mixture? (a) About 22 g mol−122\,\text{g mol}^{-1}, the simple arithmetic mean of 1616 and 28 g mol−128\,\text{g mol}^{-1}. (b) Exactly 16 g mol−116\,\text{g mol}^{-1} since the lighter gas dominates the mixture. (c) Approximately 20 g mol−120\,\text{g mol}^{-1}; it lies between 1616 and 28 g mol−128\,\text{g mol}^{-1} and is closer to 16 g mol−116\,\text{g mol}^{-1} because the mixture contains twice as many moles of CH4\mathrm{CH_4} as of N2\mathrm{N_2}. (d) Nearly 24 g mol−124\,\text{g mol}^{-1} after (incorrectly) weighting the two molar masses by their gram amounts rather than by their mole amounts.

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