Ammonia reacts with carbon dioxide and water according to with per reaction as written

CHEMISTRY · Single correct · A Level · Chemistry · Amount of substance · Amount of substance

Problem

Ammonia reacts with carbon dioxide and water according to 2 NH3(aq)+CO2(aq)+H2O(l)→(NH4)2CO3(aq)2\,\text{NH}_3(aq)+\text{CO}_2(aq)+\text{H}_2\text{O}(l)\rightarrow (\text{NH}_4)_2\text{CO}_3(aq) with ΔH=−132 kJ\Delta H=-132\,\text{kJ} per reaction as written. A reaction mixture contains 5.00 g5.00\,\text{g} of NH3\text{NH}_3, 4.40 g4.40\,\text{g} of CO2\text{CO}_2, and 3.00 g3.00\,\text{g} of H2O\text{H}_2\text{O}. After the reaction goes to completion at constant pressure, which of the following pairs gives the heat released and the mass of NH3\text{NH}_3 that remains unreacted? (a) −6.6 kJ;  1.6 g-6.6\,\text{kJ};\;1.6\,\text{g} (b) −19 kJ;  0.0 g-19\,\text{kJ};\;0.0\,\text{g} (c) −13 kJ;  1.6 g-13\,\text{kJ};\;1.6\,\text{g} (d) −13 kJ;  3.3 g-13\,\text{kJ};\;3.3\,\text{g}

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