Per disulphuric acid ( ) can be prepared by electrolytic oxidation of as 2 H _2 SO _4…

CHEMISTRY · Subjective · AP · Chemistry · Thermodynamics and Electrochemistry · Thermodynamics and Electrochemistry

Problem

Per disulphuric acid ( H2S2O8\text{H}_2\text{S}_2\text{O}_8 ) can be prepared by electrolytic oxidation of H2SO4\text{H}_2\text{SO}_4 as 2H2SO4→H2S2O8+2H++2e.2\text{H}_2\text{SO}_4 \rightarrow \text{H}_2\text{S}_2\text{O}_8 + 2\text{H}^+ + 2e. Oxygen and hydrogen are byproducts. In such an electrolysis 9.72 litre of H2\text{H}_2 and 2.35 litre of O2\text{O}_2 were generated at STP. What is the mass of H2S2O8\text{H}_2\text{S}_2\text{O}_8 formed?

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