The molar enthalpy of vaporization of water at 100 °C is 40.7 kJ mol⁻¹

CHEMISTRY · Multi-part · A Level · Chemistry · Energetics · Energetics

Problem

The molar enthalpy of vaporization of water at 100 °C is 40.7 kJ mol⁻¹, whereas the molar enthalpy of fusion at 0 °C is 6.01 kJ mol⁻¹. A student claims that freezing 1.0 g of liquid water should release nearly as much energy as condensing 1.0 g of steam because both processes involve forming intermolecular hydrogen bonds. (a) Use appropriate calculations to compare quantitatively the heat released per gram by freezing water at 0 °C and by condensing steam at 100 °C. (b) Explain, on the basis of molecular interactions and the data provided, why the student’s claim is incorrect. (c) Describe one real-world application that relies on the large quantity of energy released during the condensation of steam, and explain how the magnitude of this energy change is advantageous in that application.

Related theory

Browse the problem library