The lattice energy of KBr is

CHEMISTRY · Single correct · A Level · Chemistry · Energetics · Energetics

Problem

The lattice energy of KBr is +671 kJ mol−1+671\,\text{kJ mol}^{-1}, and the sum of the hydration enthalpies of K⁺ and Br⁻ is −676 kJ mol−1-676\,\text{kJ mol}^{-1}. What is the approximate enthalpy change, ΔHsolution\Delta H_{\text{solution}}, for dissolving 1.0 mol of KBr in a large volume of water? (a) +5 kJ mol−1+5\,\text{kJ mol}^{-1} (b) +671 kJ mol−1+671\,\text{kJ mol}^{-1} (c) −5 kJ mol−1-5\,\text{kJ mol}^{-1} (d) −1.35×103 kJ mol−1-1.35\times10^{3}\,\text{kJ mol}^{-1}

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