When a sparingly soluble salt such as is introduced into an aqueous solution that…

CHEMISTRY · Single correct · AP · Chemistry · Equilibrium · Equilibrium

Problem

When a sparingly soluble salt such as AgClAgCl is introduced into an aqueous solution that already contains a large concentration of Cl−Cl^- from dissolved NaClNaCl, which of the following statements best describes the effect on the solubility of AgClAgCl? (a) Its solubility increases because the added Cl−Cl^- drives the dissolution equilibrium to the right. (b) Its solubility decreases because the added Cl−Cl^- shifts the dissolution equilibrium toward the solid phase. (c) Its solubility remains unchanged because the solubility product constant KspK_{sp} is fixed at the given temperature. (d) Its solubility first increases and then decreases as the ionic strength of the solution rises.

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