A 3:2 molar mixture of and is present in a vessel at 500 bar pressure

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Problem

A 3:2 molar mixture of N2\text{N}_2 and CO\text{CO} is present in a vessel at 500 bar pressure. Due to hole in the vessel, the gas mixture leaks out. The composition of mixture effusing out initially is : (1) nN2:nCO::1:2n_{\text{N}_2} : n_{\text{CO}} :: 1:2 (2) nN2:nCO::6:1n_{\text{N}_2} : n_{\text{CO}} :: 6:1 (3) nCO:nN2::1:2n_{\text{CO}} : n_{\text{N}_2} :: 1:2 (4) nCO:nN2::2:3n_{\text{CO}} : n_{\text{N}_2} :: 2:3

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