A student wanted to find the enthalpy of combustion of propan-1-ol and collected the…

CHEMISTRY · Multi-part · A Level · Chemistry · Energetics · Energetics

Problem

A student wanted to find the enthalpy of combustion of propan-1-ol and collected the following data:
Initial mass of burner and propan-1-ol / g\text{g}45.65
Final mass of burner and propan-1-ol / g\text{g}45.05
Mass of water heated / g\text{g}210
Initial temperature of water / ∘C^\circ\text{C}23.7
Final temperature of water / ∘C^\circ\text{C}41.5
Specific heat capacity of water / J K−1 g−1\text{J K}^{-1}\text{ g}^{-1}4.18
(a) Calculate the amount, in mol, of propan-1-ol burnt. (b) Calculate the heat absorbed, in kJ, by the water. (c) Determine the enthalpy change, in kJ mol−1\text{kJ mol}^{-1}, for the combustion of one mole of propan-1-ol. (d) Suggest why this value differs from the literature value of −2021 kJ mol−1-2021\text{ kJ mol}^{-1}.

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