A solution is in equilibrium with excess CaF (s), NH Cl(s)

CHEMISTRY · Single correct · AP · Chemistry · Acids and Bases · Acids and Bases

Problem

A solution is in equilibrium with excess CaF2_2(s), NH4_4Cl(s), and PbS(s) at pH 8. The pH is slowly lowered to 2 while temperature remains constant. Which statement correctly predicts how the molar solubilities of the three salts will change? (a) CaF2\text{CaF}_2 decreases, NH4Cl\text{NH}_4\text{Cl} increases, PbS\text{PbS} unchanged (b) CaF2\text{CaF}_2 increases, NH4Cl\text{NH}_4\text{Cl} unchanged, PbS\text{PbS} increases (c) CaF2\text{CaF}_2 increases, NH4Cl\text{NH}_4\text{Cl} increases, PbS\text{PbS} increases (d) CaF2\text{CaF}_2 unchanged, NH4Cl\text{NH}_4\text{Cl} decreases, PbS\text{PbS} increases

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