A researcher measures the standard free energy change for a reaction and obtains at and at

CHEMISTRY · Single correct · A Level · Chemistry · Thermodynamics · Thermodynamics

Problem

A researcher measures the standard free energy change for a reaction and obtains ΔG∘=−15 kJ mol−1\Delta G^{\circ}=-15\,\text{kJ mol}^{-1} at 300 K300\,\text{K} and ΔG∘=+25 kJ mol−1\Delta G^{\circ}=+25\,\text{kJ mol}^{-1} at 800 K800\,\text{K}. Assuming ΔH∘\Delta H^{\circ} and ΔS∘\Delta S^{\circ} are constant in this temperature interval, which temperature is closest to the equilibrium point for the reaction? (a) 630 K630\,\text{K} (b) 490 K490\,\text{K} (c) 550 K550\,\text{K} (d) 740 K740\,\text{K}

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