Substance Z is 46.7 % Si and 53.3 % O by mass

CHEMISTRY · Single correct · A Level · Chemistry · Bonding · Bonding

Problem

Substance Z is 46.7 % Si and 53.3 % O by mass. It has a melting point of 1 610 °C, is extremely hard, and does not conduct electricity in the solid or molten state. Which classification of Z is most strongly supported by these observations? (a) Ionic lattice made of Si4+\text{Si}^{4+} and O2−\text{O}^{2-} ions whose strong electrostatic attractions give the substance its hardness and high melting point. (b) Network-covalent solid in which each Si atom is tetrahedrally bonded to O atoms, forming an extended SiO2\text{SiO}_2 lattice. (c) Molecular solid consisting of discrete SiO2\text{SiO}_2 molecules held together only by London dispersion forces. (d) Ionic compound of Si4+\text{Si}^{4+} and O2−\text{O}^{2-} ions that remains non-conductive when molten because the ions’ high charges keep them from moving freely.

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