When converting percent composition data into an empirical formula

CHEMISTRY · Single correct · A Level · Chemistry · Amount of substance · Amount of substance

Problem

When converting percent composition data into an empirical formula, chemists often begin by assuming that the sample has a mass of exactly 100 g100\,\text{g}. Which of the following most accurately explains why this assumption is valid? (a) Because most laboratory balances are calibrated to give their greatest precision near 100 g100\,\text{g}, so choosing that mass minimizes measurement error (b) Because selecting a 100 g100\,\text{g} basis guarantees that the numbers of moles of each element will come out to whole numbers (c) Because percent values represent parts per hundred, adopting a 100 g100\,\text{g} basis allows each percent to correspond numerically to grams without altering the elemental ratios (d) Because percent composition is only meaningful for a 100 g100\,\text{g} sample; any other sample size would change the reported percentages

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