Ammonia is synthesized industrially according to the balanced equation N₂(g) + 3…

CHEMISTRY · Multi-part · A Level · Chemistry · Thermodynamics · Thermodynamics

Problem

Ammonia is synthesized industrially according to the balanced equation N₂(g) + 3 H₂(g) ⇌ 2 NH₃(g). At 298 K, the standard enthalpy change is ΔH° = –92.4 kJ mol⁻¹ and the standard entropy change is ΔS° = –198 J mol⁻¹ K⁻¹. The gas constant is R = 8.314 J mol⁻¹ K⁻¹. (a) Calculate the standard Gibbs free-energy change ΔG° for the formation of ammonia at 298 K. Include the correct sign and units. (b) Determine the numerical value of the equilibrium constant K at 298 K. Report K to an appropriate number of significant figures. (c) Interpret the magnitude of K with respect to the extent of ammonia formation under standard conditions.

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