EMF, Terminal Voltage & Internal Resistance
Read the label on a fresh AA cell: 1.5 V. Now put that cell in a torch, switch on, and measure the voltage across its terminals: perhaps 1.32 V. Nothing is broken. No energy has vanished. The cell is simply telling you the most important secret of real electrical sources: the label voltage and the working voltage are two different quantities, and the gap between them grows with every ampere you demand. The label quantity is the electromotive force — emf, symbol — the energy the cell's chemistry hands to each coulomb of charge that passes through it. The working quantity is the terminal voltage , what a voltmeter actually reads across the terminals while current flows. They differ because every real source contains an unavoidable obstacle inside itself: the internal resistance of its own electrolyte and electrodes. Charge must pay a toll of volts just to get out of the cell, and only what remains — — is available to the outside circuit. This one equation explains why car headlights dim when the engine cranks, why a "dead" battery can still read healthy on a voltmeter, why your phone reports battery health as a percentage, and how examiners in every board build two-mark, three-mark and full-graph questions out of a single straight line. Master the budget — emf earned, spent inside, delivered — and every battery problem in the chapter becomes bookkeeping you can do in your sleep.
- Emf is the energy given to each coulomb by the source: , measured in volts. It is not a force, despite the name.
- Every real source has an internal resistance in series with its emf; the pair describes the source completely.
- With current flowing, the terminal voltage is : the emf minus the "lost volts" spent inside the cell.
- Limits and fingerprint: open circuit () reads ; short circuit caps at ; the – graph is a straight line — intercept , slope — and two loaded readings determine both.
- While charging, current is pushed backwards and the terminals read — the one case where exceeds .
- Key idea: of the joules per coulomb the chemistry provides, are spent crossing the source's own interior — the circuit outside only ever sees .
A real source is an ideal emf in series with an internal resistance , so its terminal voltage falls linearly with the current drawn, : the emf is what the chemistry pays each coulomb, the terminal voltage is what survives to the outside world, and the difference heats the source itself.
Where this lives today
Internal resistance has become one of the most closely watched numbers in consumer technology. The "battery health" percentage on a phone is, behind the marketing, largely a statement about : as lithium-ion cells age, their internal resistance creeps upward, terminal voltage sags harder under load, and the phone shuts down early even though plenty of charge remains — the modern version of the torch that dims with "fresh-looking" cells. Electric-vehicle battery-management systems run the two-reading measurement of this article continuously: they pulse a known current, watch the voltage sag, compute the slope, and log the internal resistance of every cell group as the earliest honest indicator of ageing. The cold-morning car start is still the classic demonstration. Near freezing, a lead–acid battery's electrolyte chemistry slows and its internal resistance multiplies; the starter motor's enormous current then drags the terminal voltage down so far that the dashboard dims — and, if has grown enough with age, below what the ignition electronics tolerate. Same emf, same voltmeter reading on the bench, failed start: a pure internal-resistance effect, diagnosed by exactly the physics of this module.
The physical picture
Picture the cell as a water pump inside a fenced compound, with one narrow pipe between the pump and the gate. The pump pressure is fixed by its machinery — that is the emf, set by chemistry alone. But every litre that leaves the compound must first squeeze through the narrow internal pipe, losing some pressure on the way. The pressure you measure at the gate is the pump's pressure minus the internal loss — and the faster the flow, the bigger that loss. Close the gate entirely (no flow) and the gate pressure equals the full pump pressure. Electrically: the chemical reactions inside a cell lift each coulomb through joules of energy — for the AA cell, 1.5 joules per coulomb. But the coulomb then has to travel out through the cell's own innards: electrolyte, electrode surfaces, contacts. These materials conduct, imperfectly, and their combined resistance is the internal resistance . It is not a component someone installed; it is the physical interior of the source, and no coulomb has a way around it.
Hold two consequences of the picture before any algebra. First, the toll is traffic-dependent: the internal drop is , so it vanishes when no current flows and grows with demand. A voltmeter, which draws almost nothing, therefore reads nearly the full emf — which is precisely why a voltmeter alone cannot diagnose a worn-out battery. Second, the toll is paid as heat inside the source: a battery working hard warms up, and that warmth is exactly the missing volts' worth of energy per coulomb. Nothing is lost from the books; it is just spent in the wrong shop. The emf itself comes from chemistry in a cell, but the concept is broader: a solar panel's emf comes from light, a generator's from motion (that story arrives with Electromagnetic Induction in E6). In every case the source hands each coulomb a fixed energy budget, and in every case its own interior takes a cut proportional to the current.
The budget equation
Start from the definition you met in Electric Potential & Potential Difference: potential difference is energy per charge. The emf is defined the same way, but for the source's contribution:
where: — the work done (energy transferred) by the source, in joules; — the charge driven through it, in coulombs; — the emf, in volts. A 12 V battery gives each coulomb 12 J. Despite the historical name "electromotive force", equation (1) is an energy-per-charge statement, in volts — writing "emf is the force that pushes charges" is a guaranteed lost mark on every board. Now do the accounting for a coulomb making one full lap of a simple circuit: out through the cell's interior, around the external load, and back. The chemistry pays it . Crossing the internal resistance costs (that is just Ohm's Law & Resistance applied to ). What remains when it emerges at the terminals — the energy per coulomb available to the outside — is the terminal voltage:
where: — terminal voltage, what a voltmeter across the terminals reads, in volts; — the current being drawn, in amperes; — internal resistance, in ohms. The product is the lost volts — "lost" only to the external circuit, since it reappears as heat inside the cell. Read the two limits directly from the equation: at , (open circuit reads the emf); as grows, sags linearly. Connect a load resistance across the terminals and the same coulomb must also spend crossing it. The budget must balance — — which fixes the current the circuit settles at:
where: — the total resistance of the loop, external plus internal, in series because every coulomb crosses both. This is the master equation of single-loop battery problems. Two special cases orient it: with the internal toll is negligible and — the ideal-battery regime your earlier circuit work quietly assumed. With (a short circuit) the current hits its ceiling : even a perfect wire across the terminals cannot draw more, because the source's own interior throttles it.
We want equation (2), , derived the way boards expect it justified: by following the energy of one coulomb around the circuit and insisting that every joule is accounted for. The strategy is to list what the coulomb earns and what it spends in each segment of the loop, then read off what must be left at the terminals. Watch where each term physically lives — the whole exam value of this equation is knowing which piece of hardware each symbol belongs to.
Step 1. Set the stage: a cell of emf and internal resistance drives a steady current through an external resistor . Steady current means no charge piles up anywhere, so one coulomb making a full lap must end with exactly the energy it started with.
Step 2. Earnings: passing through the chemical interior, the coulomb is lifted through joules — that is the definition of emf in equation (1).
Step 3. Spending, part one: still inside the cell, the coulomb crosses the internal resistance carrying current , which by Ohm's law costs joules per coulomb, delivered as heat to the cell's own body. Why the cost is unavoidable: r is the electrolyte and electrodes themselves — the coulomb has no alternative route from one terminal to the other through the outside-facing chemistry.
Step 4. What emerges at the terminals is therefore joules per coulomb — and "energy per coulomb available between two points" is precisely what a voltmeter measures. So the terminal voltage is : equation (2).
Step 5. Close the loop for consistency: the coulomb spends its remaining joules crossing the external resistor, . Substituting gives , which is equation (3). One budget, three equations, zero leftover joules. Verified: with ε = 6.0 V, r = 0.5 Ω, R = 11.5 Ω: I = 6.0/12.0 = 0.50 A, V = 6.0 − 0.25 = 5.75 V = IR = 0.50 × 11.5 ✓ — the audit balances.
One more reading of equation (2) earns marks surprisingly often: solve it for the efficiency of delivery. The fraction of the chemistry's energy that reaches the outside is . A torch running a bulb from a cell with delivers of its energy usefully; short the same cell and the efficiency is zero — every joule cooks the cell. (Which load extracts the maximum power is a different, sneakier question — the classic answer — and it gets its full treatment in the battery-problems archetype coming later in this chapter.)
The V–I graph: a battery's fingerprint
Equation (2) is a straight line, and examiners love straight lines. Plot terminal voltage (vertical) against current drawn (horizontal) and a real battery traces a falling line: it starts at on the voltage axis (the open-circuit reading), drops with slope , and would hit the current axis at (the short-circuit current). Every battery question with a graph in it is asking you to read one or more of those three features.
The graph is also a measuring instrument. Take two readings under different loads — and — and equation (2) written twice gives two simultaneous equations in the two unknowns and . Subtracting them cancels :
where: the ordering matters — the reading with the larger current has the smaller voltage, so both differences are positive when you pair them correctly. In words: internal resistance is the sag in voltage per extra ampere of demand. Back-substitute either reading to get . This two-point method is the standard school practical, and the competitive worked example below runs it end to end. One direction of travel remains. Push current backwards through the cell — which is exactly what a charger does — and the internal drop changes sides: the charger must overcome both the emf and the toll, so the terminals read
where: — the charging current forced through the cell. This is the only situation in this chapter where the terminal voltage exceeds the emf, and it is why a phone battery whose cell emf is 3.7 V shows about 4.0 V across it while fast-charging, and why a running car holds its 12.6 V battery at roughly 14 V. Spotting "charging" in a question and flipping the sign is a one-mark decision that many candidates miss under time pressure.
Limiting cases
| case | result | meaning |
|---|---|---|
| (open circuit) | no traffic, no toll — a voltmeter alone reads the emf | |
| (short circuit) | , | the source's interior caps the current; all energy heats the cell |
| at any load | the "ideal battery" of earlier chapters — a useful fiction | |
| , efficiency | well-designed loads barely notice the internal resistance | |
| charging ( reversed) | terminals read above the emf — the sign flip exams test | |
| grows with age | same , steeper – slope | why old batteries pass a voltmeter check and fail under load |
Worked examples
Board level — the torch circuit budget (CBSE/ICSE pattern, 3 marks)
A battery of emf and internal resistance is connected to a lamp of resistance . Find (a) the current in the circuit, (b) the terminal voltage of the battery, and (c) the largest current this battery could ever supply.
Step 1. Part (a), from equation (3): the loop's total resistance is , so .
Step 2. Part (b), two equivalent routes — use one, check with the other. Budget route: . Check via the load: ✓. The lost volts are — energy heating the battery, not the lamp.
Step 3. Part (c): the ceiling is the short-circuit current, — no external circuit, however greedy, can pull more.
Step 4. The sentence that earns the method mark: "The battery delivers ; the difference between emf and terminal voltage is the potential drop across the internal resistance." Stating equation (2) in words, with each symbol placed in its hardware, is what the scheme is looking for.
Competitive level — two readings and a backwards battery (JEE-Main pattern, ~3 minutes)
A cell drives through a resistor. When the resistor is replaced by a one, the current rises to . Find (a) the emf and internal resistance of the cell, (b) the terminal voltage in the second case, and (c) the terminal voltage if this cell is instead charged at .
Step 1. Write equation (3) twice, as : and .
Step 2. Set them equal and solve: , so , giving . Back-substitute: .
Step 3. Part (b): — or via the budget, ✓. Notice the sanity pattern: the heavier load (smaller , larger ) shows the lower terminal voltage. If your simultaneous equations ever produce a negative , you have paired the readings wrongly — larger current must go with smaller resistance.
Step 4. Part (c) is the sign flip: charging reverses the current through the cell, so equation (5) applies: . The charger must present 3.0 V to force 2.0 A backwards through this cell. Timing note: about 3 minutes. The subtraction trick — divide the two ε-equations or subtract them so ε cancels — should be automatic; do not solve by substitution under exam time. The charging flip in (c) is a five-second decision worth a full mark: spot the word "charged", change the sign.
Exam traps
Calling emf a force. Emf is energy per unit charge, in volts — equation (1). The name is an eighteenth-century fossil. Boards from CBSE to A-Level explicitly award or dock the definitional mark on this point.
Using where belongs (and vice versa). In , the numerator is the emf, never the loaded terminal voltage. Conversely the power delivered to the external circuit is , not (that is the total including internal heating). Place each symbol in its hardware before substituting numbers.
Assuming the voltmeter reads the emf exactly. It reads the emf only if it draws truly zero current. School voltmeters are high-resistance, so the reading is close to — good enough at board level when stated, but "the voltmeter reads slightly less than the emf because it draws a small current" is the full-credit sentence. (The instrument that genuinely draws zero at balance is the potentiometer — a story for later in this chapter.)
The charging sign. "A battery is being charged at…" flips equation (2) to . Terminal voltage above emf is not an error; it is the signature of charging.
Graph-reading slips. On a – graph the intercept is and the slope is : a steeper line means a worse (higher-resistance) source. Do not report the slope with a positive sign, and do not confuse this graph with the – characteristic of a resistor from Ohm's Law & Resistance — here the falling line belongs to the source.
Pairing errors in two-reading problems. Bigger goes with smaller . A negative from your algebra is the standard symptom of mispairing — treat it as an alarm, not an answer.
Constants and conventions. All boards here work in SI volts, amperes, ohms. No is needed anywhere in this module. IB and AP-2 papers typically give explicitly; JEE and NEET expect you to extract it from data or graphs as in the competitive example.
Origins · 1 minJohn Frederic Daniell and how this was discovered
Volta's pile had a fatal flaw for practical use: within minutes, hydrogen bubbles coated its copper plates and the current faded — an effect called polarisation, which in modern language is a runaway growth of internal resistance while the cell works. John Frederic Daniell, the first professor of chemistry at King's College London, solved it in 1836 with a two-fluid cell: zinc in dilute sulfate on one side, copper in copper-sulfate solution on the other, separated by a porous pot. The copper ions accepted the arriving electrons cleanly, no gas film formed, and the Daniell cell held a steady 1.1 volts for hours at a time. It became the workhorse of the young telegraph industry — the first technology to demand a source with dependable emf and tame internal resistance — and for decades the "standard cell" against which voltages were calibrated: when physicists first defined the volt practically, they described it as roughly the emf of one Daniell cell.
Going further
Texts. NCERT Physics Class 12, Ch. 3 (Current Electricity, cells and emf sections) · HC Verma, Concepts of Physics Vol. 2, Ch. 32 · CIE 9702 Topic 10 (practical circuits: emf and internal resistance) · IB Physics guide, Theme B.5.
Provenance. All results are standard. A verifier should recompute: Example 1's , both routes, , efficiency ; Example 2's , , , charging ; quiz values , , , .
Prerequisites. Electric Potential & Potential Difference · Ohm's Law & Resistance. Leads to. Combining Cells: Series & Parallel · Kirchhoff's Rules · the battery-problems archetype (maximum power, efficiency — coming later in E3) · EMF and Internal Resistance (UG deep dive).
Is emf a kind of force or a kind of voltage? The name confuses me every time.
It is a voltage-like quantity: energy per unit charge, measured in volts, exactly like potential difference. The name "electromotive force" was coined before physicists had cleanly separated force from energy, and it stuck. The real distinction worth keeping is not force-versus-voltage but origin: a potential difference is measured between two points of a circuit, while an emf is the energy per coulomb injected by a source — by chemistry here, by changing magnetic flux when you reach Electromagnetic Induction. On paper they share units; in the energy budget they sit on opposite sides of the ledger. Exams test exactly this sentence: "emf is the work done per unit charge by the source, measured in volts; it is not a force."
Where exactly is the internal resistance? Can I open a battery and point at it?
You can point at almost everything inside. The internal resistance is not a hidden component but the resistance of the cell's own working parts: the electrolyte the ions must swim through, the electrode surfaces where the chemistry happens, the separators and contacts. That is why nobody can remove it, and why it changes with the cell's condition — a cold electrolyte conducts worse (higher ), an aged electrode is partly clogged (higher ), a nearly flat cell has depleted chemistry (much higher ). Treat as a snapshot of the source's health, not a permanent label.
Why does the voltage come back after I switch the torch off? It reads 1.5 V again like nothing happened.
Because the lost volts exist only while current flows. The internal drop is — switch off, , and the drop vanishes instantly, so the terminals show the full emf again. Nothing "recovers"; the toll booth simply has no traffic. This is also why the open-circuit reading is so misleading about battery health: it is taken at exactly the operating point where internal resistance is invisible. (A tired cell's chemistry also recovers slightly with rest, but the instant jump back to 1.5 V is pure disappearing.)
Can the terminal voltage ever be larger than the emf, or is V = ε − Ir an absolute ceiling?
It can be larger — during charging. Force current backwards through the cell and the internal drop flips to the other side of the budget: the charger must supply to overcome both the chemistry and the toll. Your phone shows about 4.0 V across a 3.7 V cell while fast-charging; a running car holds its 12.6 V battery near 14 V. Discharging: below . Charging: above . Equal: no current at all. Examiners plant the word "charged" quietly in part (c) of a question and award a full mark for the sign flip alone.
If short-circuiting gives the maximum current, why is short-circuiting a battery dangerous rather than useful?
Because every one of those amperes dumps its energy inside the cell. At short circuit the external voltage is zero, so the entire budget becomes internal heating — for a car battery, hundreds of amperes cooking the cell's own electrolyte. That is a fire and rupture hazard, not a power supply. Useful power delivery needs the energy spent outside: efficiency is , which is zero at short circuit and approaches 100% when . Maximum current and useful operation sit at opposite ends of the fingerprint line.
My textbook says a voltmeter measures emf on open circuit, but doesn't the voltmeter itself draw some current?
It does, and your suspicion is exactly right — the statement is an approximation. A real voltmeter has very high but finite resistance, so it draws a tiny current and reads , a whisker below the true emf. For a school cell ( under an ohm) and a digital meter (megohms), the error is microvolts — utterly negligible. But the principle matters and boards reward it: only a measurement drawing genuinely zero current reads the emf exactly — the instrument built to achieve that, the potentiometer, balances voltages until no current flows, and it has its own module later in this chapter.
Why do the headlights dim when the engine starts but recover once it is running?
Cranking, the starter motor demands a huge current — order of a hundred amperes — through the battery's small internal resistance, so the terminal voltage sags by , several volts, and everything wired to the battery (headlights included) momentarily runs undervoltaged and dim. Once the engine runs, two things restore the brightness: the starter stops drawing its current, and the alternator takes over, actually charging the battery and holding the electrical system near 14 V. The dim-and-recover cycle is the whole of this module playing out on your dashboard: sag by , recovery into .
Is internal resistance constant for a given cell, like the resistance of a resistor?
Treat it as constant within one problem — that is the model every board uses, and it makes the fingerprint line straight. Physically it drifts: up as the cell discharges (chemistry depleting), up in the cold (slower ion transport), up with age (electrode degradation), and it even differs between charging and discharging directions in real lithium cells. This is why a battery datasheet quotes internal resistance at a stated temperature and state of charge. The exam-honest sentence: " is approximately constant over the currents considered, but in reality varies with temperature, age and state of charge."