Rutherford nuclear model
Fire a beam of fast, positively charged alpha particles at a sheet of gold foil only a few hundred atoms thick, and almost every particle sails straight through as if the foil were mostly empty space. But every so often — about once in eight thousand — a particle bounces almost straight back, as Rutherford famously put it, "as if you fired a fifteen-inch shell at a piece of tissue paper and it came back and hit you." That single startling result overturned the reigning picture of the atom and replaced it with one we still use today: a tiny, dense, positively charged nucleus at the centre, with electrons revolving around it through mostly empty space. This article rebuilds that reasoning from the Geiger–Marsden scattering data to the energy argument that lets you estimate how small the nucleus actually is.
Large-angle and back-scattering of alpha particles off a thin gold foil is only possible if an atom's positive charge and most of its mass are concentrated in a tiny central nucleus, and equating an alpha particle's kinetic energy to the electrostatic potential energy at closest head-on approach gives a nuclear size of order m.
The core idea
The experiment. In the Geiger–Marsden setup, a narrow beam of alpha particles (, charge ) from a radioactive source was aimed at a thin gold foil (about m thick), and a rotatable zinc-sulphide screen counted scintillation flashes at every scattering angle around the foil. Three observations had to be explained together: most alpha particles passed through with little or no deflection; a small fraction deflected through large angles, well beyond ; and a very small fraction (roughly 1 in 8000) bounced back at angles close to .
Why Thomson's model failed. In Thomson's earlier "plum-pudding" picture, positive charge was spread smoothly through the whole atom, like a diffuse cloud with electrons studded inside it. A charge spread that thinly can only push an incoming alpha particle a little — the repulsion at any point is weak because the charge nearby is small. Such a model can account for the small deflections but has no mechanism at all for throwing a fast, heavy alpha particle almost straight back. The back-scattering data alone ruled it out.
Rutherford's model. To produce occasional sharp, large-angle deflections, Rutherford proposed that an atom's positive charge and nearly all its mass are concentrated in an extremely small region at the centre — the nucleus — with electrons orbiting it at comparatively enormous distances, held by electrostatic attraction so the atom is neutral overall. Most of the atom's volume is then empty space, which is why the great majority of alpha particles pass through undisturbed; only the rare particle that happens to aim almost directly at a nucleus feels a strong enough repulsive Coulomb force to swing through a large angle or rebound.
Estimating nuclear size. For a head-on collision, the alpha particle slows down as it approaches the nucleus and momentarily stops at the point of closest approach , where all of its initial kinetic energy has converted into electrostatic potential energy:
where: is the alpha particle's initial kinetic energy far from the nucleus, is the alpha particle's charge, is the nuclear charge for atomic number , is the permittivity of free space (folded into Coulomb's constant ), and is the distance of closest approach. Solving for gives an upper bound on the nuclear radius, since a real alpha particle only reaches the nuclear surface if it happens to have enough energy and is aimed exactly head-on. Experiments of this kind consistently give
— about ten thousand times smaller than the size of the atom as a whole (), confirming that the nucleus is an extremely small, dense core carrying essentially all the atom's mass. Within this model, the atomic number is the number of protons (equal to the number of electrons in a neutral atom), the neutron number is , and the mass number gives the total number of nucleons packed into that tiny core.
The goal is to turn a measured alpha-particle kinetic energy and a target atomic number into a numerical estimate of how close the particle can get to the nucleus in a head-on collision — the same energy-conservation argument that let Rutherford place an upper bound on nuclear size using nothing beyond Coulomb's law and the work-energy idea, with no scattering-angle theory required.
Step 1. Picture the head-on collision. Far from the nucleus, the alpha particle moves with speed and kinetic energy ; the potential energy is taken as zero there. As it approaches the (much heavier, effectively fixed) nucleus, the repulsive Coulomb force does negative work on it, converting kinetic energy into electrostatic potential energy , which grows without bound as the separation shrinks.
Step 2. At the instant of closest approach, the alpha particle is momentarily at rest (for a truly head-on shot) before the repulsion pushes it back out the way it came. At that instant all the initial kinetic energy has become potential energy, so energy conservation gives , that is .
Step 3. Rearrange for : . This shows grows with the target's atomic number (a more highly charged nucleus repels harder) and shrinks as the alpha particle's kinetic energy increases (a faster particle can force its way closer before stopping).
Step 4. Read the result physically. The measured value of , for high-energy alpha particles, is an upper bound on the true nuclear radius — the particle stops just outside the nucleus if exceeds the nuclear surface, but if the calculation gives an smaller than the true nuclear radius, the particle actually penetrates and the pure Coulomb formula no longer applies, since short-range nuclear forces take over. Consistent estimates across many experiments converge on , which is why the fermi () is the natural unit for nuclear sizes.
Worked example
An alpha particle with kinetic energy is fired head-on at a stationary gold nucleus (). Find the distance of closest approach.
Step 1. Convert the energy to joules: .
Step 2. Write the closest-approach relation from the derivation above: , with , and .
Step 3. Compute the numerator: .
Step 4. Divide by : , about .
This is larger than the true nuclear radius of gold, because a 5 MeV alpha particle simply does not carry enough energy to force its way in to the actual nuclear surface — it stops well outside and gets deflected back before ever "feeling" the nucleus directly. Higher-energy alpha particles push down toward the true nuclear scale of a few femtometres.
Competitive stretch
For the same gold nucleus, what closest-approach distance would a alpha particle reach? Since , scaling the previous answer by the energy ratio gives — now within a factor of a few of gold's actual nuclear radius, which is why physicists used progressively higher-energy beams to pin down real nuclear sizes.
Common traps
- Treating the distance of closest approach as the nuclear radius rather than an upper bound on it — the formula assumes a purely electrostatic, head-on interaction and stops applying once the particle would otherwise penetrate the nucleus.
- Using charge instead of for the alpha particle, or instead of for the target nucleus — a very common arithmetic slip that changes the answer by a large factor.
- Assuming the Thomson model was ruled out simply because particles were deflected at all — small deflections are expected from any charge distribution; it is specifically the rare large-angle and back-scattering events that only a concentrated central charge can produce.
- Attempting to invoke the full Rutherford scattering formula with impact parameter and differential cross-section — this is outside the ISC syllabus, which requires only the qualitative model and the energy-conservation estimate of .
Ask the tutor: want to work through how the distance of closest approach changes for a different target nucleus or a different beam energy, step by step?
Why does a bigger atomic number Z give a larger distance of closest approach?
Because is directly proportional to . A nucleus with more protons carries a larger positive charge , so it repels an incoming alpha particle more strongly at any given separation. That stronger repulsion brings the alpha particle to a halt sooner — that is, at a larger — for the same initial kinetic energy. This is exactly why gold () produces much more back-scattering than a lighter foil would at the same beam energy.
If the formula gives r0 = 45.5 fm for a 5 MeV alpha particle on gold, does that mean gold's nucleus is really that big?
No. That number is only an upper bound reached under the assumption that the interaction stays purely electrostatic all the way in. The true radius of a gold nucleus is only a few femtometres. A 5 MeV alpha particle simply never gets close enough to feel anything besides the Coulomb repulsion, so it stops and turns back well outside the real nuclear surface. To probe closer to the true radius, experimenters use higher-energy alpha particles, which shrink toward the nucleus's actual size.
Why does most of the atom counted as empty space if electrons are actually there?
Electrons occupy an atom's outer region, but they contribute almost nothing to blocking or scattering a fast, comparatively heavy alpha particle — their mass is thousands of times smaller and their charge is spread over a huge volume compared with the nucleus. So while electrons are technically present throughout the atom, from the alpha particle's point of view the vast space between the tiny central nucleus and the atom's outer edge behaves as if it were essentially empty, which is why the overwhelming majority of particles pass through with negligible deflection.